{"title":"Porous Materials","description":null,"products":[{"product_id":"cgasmofmil53al","title":"MIL-53(Al) Metal Organic Frameworks (MOFs) Powder for Gas Absorption and Separation, CGASMOFMIL53Al","description":"\u003cp\u003eMIL-53(Al) (Materials of Institut Lavoisier-53, aluminum terephthalate, Al(OH)[O2C–C6H4–CO2) is one of the most widely studied flexible Metal-Organic Frameworks (MOFs). Constructed from corner-sharing AlO4(OH)2 octahedral chains cross-linked by 1,4-benzenedicarboxylate (BDC) linkers, it forms 1D rhombic diamond-shaped pore channels known for their reversible structural transitions.\u003c\/p\u003e\n\u003cp\u003eThe critical features of the MIL-53(Al) are shown below: (1) \u003cstrong\u003eReversible \"Breathing Effect\"\u003c\/strong\u003e: MIL-53(Al) transitions between a Large Pore (LP) form (open diamond channel, pore diameter ~ 8.5–12Å, unit cell volume ~ 1480Å^3) and a Narrow Pore (NP) form (contracted channel, pore diameter ~ 2.6–3.5\u003cspan\u003eÅ\u003c\/span\u003e, unit cell volume ~ 1000\u003cspan\u003eÅ\u003c\/span\u003e^3). This transition is triggered by guest molecule adsorption, temperature, or external mechanical pressure. (2) \u003cstrong\u003eHigh Hydrothermal \u0026amp; Thermal Stability\u003c\/strong\u003e: Unlike many zinc- or copper-based MOFs (such as MOF-5 or HKUST-1), MIL-53(Al) resists moisture degradation and remains thermally stable up to ~ 450–500°C in air\/inert environments. (3) \u003cstrong\u003eTextural Properties\u003c\/strong\u003e: \u003cem\u003eBET Surface Area\u003c\/em\u003e: Typically 1100–1600 m2\/g (depending on activation and synthesis route).\u003c\/p\u003e\n\u003ctable border=\"1\" style=\"width: 100.071%; height: 257.125px;\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003ePart Number\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eCGASMOFMIL53Al (C-GAS-MOF-MIL53Al)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eCAS\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e654061-20-8\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eColor\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eWhite Powder\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eSize\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e50-200 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003eBET\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e\u0026gt;1000 m2\/g\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003ePore Size\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e0.4-0.8 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 71.2px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 71.2px;\"\u003e\u003cem\u003ePrimary Applications\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 71.2px;\"\u003e\n\u003cp\u003eGas absorption, storage, and separation. \u003c\/p\u003e\n\u003cp\u003eWastewater treatment, ion separation, \u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 24.675px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 24.675px;\"\u003e\u003cem\u003ePackage Grade\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 24.675px;\"\u003e5 g, 10 g, and 20 g\/bottle\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e\u003cb\u003e\u003cbr\u003e\u003c\/b\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cb\u003eReferences:\u003c\/b\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cb\u003e\u003c\/b\u003e\u003ca href=\"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/abs\/10.1002\/adfm.201200084\"\u003eF. Zhang, et al., Hydrogen Selective NH2-MIL-53(Al) MOF Membranes with High Permeability, Adv. Funct. Mater., 2012, 22, 3583-3590.\u003c\/a\u003e\n\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"https:\/\/pubs.acs.org\/iecred\/article-abstract\/53\/51\/19747\/1568650\/Adsorption-and-Separation-of-Carbon-Dioxide-Using?redirectedFrom=fulltext\"\u003eP. Mishra, et al., Adsorption and Separation of Carbon Dioxide Using MIL-53(Al) Metal-Organic Framework, Ind. Eng. Chem. Res. (2014) 53 (51): 19747–19753.\u003c\/a\u003e\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"TYXC","offers":[{"title":"5 g","offer_id":48247258284262,"sku":"CGASMOFMIL53AlW5","price":199.0,"currency_code":"USD","in_stock":true},{"title":"10 g","offer_id":48247258317030,"sku":"CGASMOFMIL53AlW10","price":369.0,"currency_code":"USD","in_stock":true},{"title":"20 g","offer_id":48247258349798,"sku":"CGASMOFMIL53AlW20","price":699.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CGASMOFMIL53Al_main.jpg?v=1787805425"}],"url":"https:\/\/echemsupplies.com\/collections\/porous-materials.oembed","provider":"EChem Supplies","version":"1.0","type":"link"}