{"product_id":"cbssepczc","title":"Zirconia Chloride (ZrCl4, Anhydrous, 99.99%) Precursor Powder for Halide Solid-State Electrolyte Synthesis, 25 o 50 g\/bottle, CBSSEPCZC","description":"\u003cp\u003eZirconium(IV) chloride (ZrCl4) has emerged as a crucial precursor for next-generation halide solid-state electrolytes (SSEs), such as Li2ZrCl6 and Li2Zr{1-x}FexCl6. As researchers shift away from expensive, scarce trivalent metals like Indium (In) and Yttrium (Y), the use of tetravalent Zirconium (Zr^{4+}) offers a highly cost-effective, earth-abundant alternative while maintaining excellent oxidation stability (\u0026gt;4.5 V vs. Li\/Li+) against high-voltage cathodes. However, ZrCl4 exhibits distinct physical and chemical properties—specifically sublimation and unique hydrolysis pathways—that make its handling and synthesis processing significantly different from LiCl or InCl3.\u003c\/p\u003e\n\u003cp\u003eBecause of the high volatility of ZrCl4 during direct heating, high-energy mechanochemical synthesis is the preferred method to fix zirconium into a stable framework before any thermal processing. (1) \u003cstrong\u003eMixing\u003c\/strong\u003e: Anhydrous LiCl and ZrCl4 are blended stoichiometrically under dry Argon (H2O\/O2 \u0026lt; 0.1 ppm). (2) \u003cstrong\u003eMilling\u003c\/strong\u003e: The mix is processed in a planetary ball mill (typically 400–500 RPM for 12–24 hours) using zirconia or tungsten carbide (WC) media. This forces the formation of a metastable, amorphous, or hexagonal close-packed (hcp) Li2ZrCl6 phase directly at room temperature. (3) \u003cstrong\u003eControlled Annealing\u003c\/strong\u003e: The ball-milled powder is sealed inside a quartz ampoule under deep vacuum and annealed at 250°C to 350°C to enhance crystallinity without inducing phase separation or sublimation.\u003c\/p\u003e\n\u003ctable width=\"100%\" style=\"width: 100%; height: 367.288px;\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 46.8875px;\"\u003e\n\u003ctd style=\"width: 30.6028%; height: 46.8875px;\"\u003e\u003cem\u003ePart Number\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.0375%; height: 46.8875px;\"\u003e\n\u003cp\u003e\u003cspan\u003eCBSSEPCZC (C-BSSE-PC-ZC)\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 30.6028%; height: 35.6px;\"\u003e\u003cem\u003eCAS\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.0375%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003e10026-11-6\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 30.6028%; height: 35.6px;\"\u003e\u003cem\u003ePurity\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.0375%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003e\u0026gt;99.99%\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 30.6028%; height: 35.6px;\"\u003e\u003cem\u003eMolecular Weight\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.0375%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003e233.04 g\/mol\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 30.6028%; height: 35.6px;\"\u003e\u003cem\u003eDensity \u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.0375%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003e2.8 g\/mL at 25 °C(lit.)\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 30.6028%; height: 35.6px;\"\u003e\u003cem\u003eMelt Point\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.0375%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003e437 °C\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 30.6028%; height: 35.6px;\"\u003eWater Level\u003c\/td\u003e\n\u003ctd style=\"width: 69.0375%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003e\u0026lt;100 ppm (anhydrous)\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 30.6028%; height: 35.6px;\"\u003ePackage Grade\u003c\/td\u003e\n\u003ctd style=\"width: 69.0375%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003e25 g or 50 g\/bottle\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e \u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eNotes\u003c\/strong\u003e: (1) Please store the ZrCl4 powder in a dry place (glovebox is preferred due to its air\/humidity sensitivity).\u003c\/span\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eReferences\u003c\/strong\u003e: \u003c\/span\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\u003ca href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acsami.4c08915\"\u003e\u003cspan\u003eH. Kwak, et al. Tuning the Properties of Halide Nanocomposite Solid Electrolytes with Diverse Oxides for All-Solid-State Batteries, ACS Appl. Mater. Interfaces 2024, 16, 37, 49328–49336\u003c\/span\u003e\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acsenergylett.2c00438\"\u003e\u003cspan\u003eH. Kwak, et al. Emerging Halide Superionic Conductors for All-Solid-State Batteries: Design, Synthesis, and Practical Applications, ACS Energy Lett. 2022, 7, 5, 1776–1805 \u003c\/span\u003e\u003c\/a\u003e\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"MKL","offers":[{"title":"25 g","offer_id":47749245370598,"sku":"CBSSEPCZC25","price":99.0,"currency_code":"USD","in_stock":true},{"title":"50 g","offer_id":47749245403366,"sku":"CBSSEPCZC50","price":179.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CBSSEPCZC_mian.png?v=1780685931","url":"https:\/\/echemsupplies.com\/products\/cbssepczc","provider":"EChem Supplies","version":"1.0","type":"link"}