{"product_id":"cgasmofmil100al","title":"MIL-100(Al) Metal Organic Frameworks (MOFs) Powder for Gas Absorption and Separation, CGASMOFMIL100Al","description":"\u003cp\u003eMIL-100(Al) (Al3O(X)(H2O)2(BTC)2, where X = OH-, Cl-, or F-; BTC = benzene-1,3,5-tricarboxylate}) is a lightweight, mesoporous aluminum-based metal-organic framework with an MTN zeolite-type topology. Built from inorganic u3-oxo-centered aluminum trimers (Al3O) bridged by rigid, tritopic trimesate linkers into giant supertetrahedra, it combines high pore volume and strong Lewis acidity with non-toxicity, high hydrothermal stability, and lower raw material costs.\u003c\/p\u003e\n\u003cp\u003eFor Gas Absorption \u0026amp; Separation, the key structural features of the MIL-100(Al) are: (1) \u003cstrong\u003eHierarchical MTN Dual-Mesoporous Network\u003c\/strong\u003e: \u003cem\u003eSmall Mesoporous Cages\u003c\/em\u003e: ~ 25 Å internal diameter with pentagonal window apertures of ~ 4.7-5.5 Å. \u003cem\u003eLarge Mesoporous Cages\u003c\/em\u003e: ~ 29 Å internal diameter with hexagonal window apertures of ~ 8.6 Å. (2) \u003cstrong\u003eThermal \u0026amp; Hydrothermal Resilience\u003c\/strong\u003e: The strong ionic\/covalent Al(III)–O coordination bond yields thermal stability up to~ 350–380°C in air\/inert environments. It withstands boiling water, repeated humidity cycling, and organic solvents without framework hydrolysis. (3) \u003cstrong\u003eLewis Acidic Al^{3+} Sites\u003c\/strong\u003e: Thermal evacuation strips coordinated terminal water molecules from the Al3O trimers, exposing hard Lewis acidic Al^{3+} open metal sites that strongly interact with polar, polarizable, or basic guest molecules.\u003c\/p\u003e\n\u003ctable border=\"1\" style=\"width: 100.071%; height: 292.725px;\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003ePart Number\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eCGASMOFMIL100Al (C-GAS-MOF-MIL100Al)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eCAS\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e1200358-58-2\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eColor\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eWhite Powder\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eAverage Sizes\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e~2000-5000 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003eBET\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e\u0026gt;700 m2\/g\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003ePore Size\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e0.4-1.0 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 106.8px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 106.8px;\"\u003e\u003cem\u003ePrimary Applications\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 106.8px;\"\u003e\n\u003cp\u003eGas absorption, storage, and separation. \u003c\/p\u003e\n\u003cp\u003eWastewater treatment, ion separation\u003c\/p\u003e\n\u003cp\u003eHeterogeneous catalysis \u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 24.675px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 24.675px;\"\u003e\u003cem\u003ePackage Grade\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 24.675px;\"\u003e5 g\/bottle\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e\u003cb\u003e\u003cbr\u003e\u003c\/b\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cb\u003eReferences:\u003c\/b\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cb\u003e\u003c\/b\u003e\u003ca href=\"https:\/\/pubs.acs.org\/acsccc\/article-abstract\/15\/2\/111\/1483114\/Experimental-Screening-of-Porous-Materials-for?redirectedFrom=fulltext\"\u003eA. D. Wiersum, et al., Experimental Screening of Porous Materials for High Pressure Gas Adsorption and Evaluation in Gas Separations: Application to MOFs (MIL-100 and CAU-10), ACS Comb. Sci. (2013) 15 (2): 111–119.\u003c\/a\u003e\u003ca href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S1387181123005371\"\u003e\u003c\/a\u003e\n\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"https:\/\/pubs.rsc.org\/ta\/article-abstract\/9\/38\/21483\/749920\/Aluminium-based-MIL-100-Al-and-MIL-101-Al-metal\"\u003eT. Steenhaut, et al., Aluminium-based MIL-100(Al) and MIL-101(Al) metal–organic frameworks, derivative materials and composites: synthesis, structure, properties and applications, J. Mater. Chem. A (2021) 9 (38): 21483–21509.\u003c\/a\u003e\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"TYXC","offers":[{"title":"Default Title","offer_id":48257759903974,"sku":"CGASMOFMIL100Al","price":899.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CGASMOFMIL100Al_main.jpg?v=1788032831","url":"https:\/\/echemsupplies.com\/products\/cgasmofmil100al","provider":"EChem Supplies","version":"1.0","type":"link"}