{"product_id":"cgasmofmil100fe","title":"MIL-100(Fe) Metal Organic Frameworks (MOFs) Powder for Gas Absorption and Separation, CGASMOFMIL100Fe","description":"\u003cp\u003eMIL-100(Fe) (Fe3O(X)(H2O)2({BTC)2, where X = OH- or F-; BTC = benzene-1,3,5-tricarboxylate) is an iron-based metal-organic framework with an MTN zeolite-type topology. Built from inorganic u3-oxo-centered iron trimers (Fe3O) cross-linked by trimesate ligands into rigid supertetrahedral cages, it stands out for its high mesoporous capacity, low toxicity, water stability, and tunable Fe3+\/Fe2+ open metal sites.\u003c\/p\u003e\n\u003cp\u003eFor Gas Absorption \u0026amp; Separation, the key structural features of the MIL-100(Fe) are: (1) \u003cstrong\u003eHierarchical MTN Pore Network\u003c\/strong\u003e: \u003cem\u003eSmall Mesoporous Cages\u003c\/em\u003e: ~ 25 Å internal diameter with pentagonal window apertures of ~ 5.5 Å. \u003cem\u003eLarge Mesoporous Cages\u003c\/em\u003e: ~ 29 Å internal diameter with hexagonal window apertures of ~ 8.6 Å. \u003cem\u003eSupertetrahedral Micro-Pockets\u003c\/em\u003e: ~ 7 Å vertices formed by trimer units.  (2) \u003cstrong\u003eCoordinatively Unsaturated Iron Sites (CUS)\u003c\/strong\u003e: Removing axial terminal water molecules and terminal ligands exposes open Fe3+ Lewis acid sites. Controlled higher-temperature vacuum activation enables partial auto-reduction to coordinatively unsaturated Fe2+ sites, creating strong π-backbonding capabilities.\u003c\/p\u003e\n\u003ctable border=\"1\" style=\"width: 100.071%; height: 257.125px;\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003ePart Number\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eCGASMOFMIL100Fe (C-GAS-MOFMIL100Fe)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eCAS\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e1195763-37-1\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eColor\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eBrown Powder\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eAverage Sizes\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e~100-1000 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003eBET\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e\u0026gt;1600 m2\/g\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003ePore Size\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e0.3-1.2 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 71.2px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 71.2px;\"\u003e\u003cem\u003ePrimary Applications\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 71.2px;\"\u003e\n\u003cp\u003eGas absorption, storage, and separation. \u003c\/p\u003e\n\u003cp\u003eWastewater treatment, ion separation\u003c\/p\u003e\n\u003cp\u003eHeterogeneous catalysis \u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 24.675px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 24.675px;\"\u003e\u003cem\u003ePackage Grade\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 24.675px;\"\u003e5-20 g\/bottle\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e\u003cb\u003e\u003cbr\u003e\u003c\/b\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cb\u003eReferences:\u003c\/b\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cb\u003e\u003c\/b\u003e\u003ca href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S1385894718316784\"\u003eB. Yuan, et al., Novel room-temperature synthesis of MIL-100(Fe) and its excellent adsorption performances for separation of light hydrocarbons, Chemical Engineering Journal, 2019, 355, 679-686\u003c\/a\u003e\u003ca href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S1387181123005371\"\u003e\u003c\/a\u003e\n\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S138718111100641X\"\u003eM. G. Plaza, et al., Separation of C3\/C4 hydrocarbon mixtures by adsorption using a mesoporous iron MOF: MIL-100(Fe), Microporous and Mesoporous Materials, 2012, 153, 178-190\u003c\/a\u003e\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"TYXC","offers":[{"title":"5 g","offer_id":48250957791462,"sku":"CGASMOFMIL100FeW5","price":229.0,"currency_code":"USD","in_stock":true},{"title":"10 g","offer_id":48250957824230,"sku":"CGASMOFMIL100FeW10","price":419.0,"currency_code":"USD","in_stock":true},{"title":"20 g","offer_id":48250957856998,"sku":"CGASMOFMIL100FeW20","price":799.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CGASMOFMIL100Fe_main.jpg?v=1787894711","url":"https:\/\/echemsupplies.com\/products\/cgasmofmil100fe","provider":"EChem Supplies","version":"1.0","type":"link"}