{"product_id":"cgasmofmil101fe","title":"MIL-101(Fe) Metal Organic Frameworks (MOFs) Powder for Gas Absorption and Separation, CGASMOFMIL101Fe","description":"\u003cp\u003eMIL-101(Fe) (Fe3O(X)(H2O)2(BDC)3, where X = Cl-, OH-, or F-; BDC = 1,4-benzenedicarboxylate) is an iron-based mesoporous metal-organic framework with an augmented MTN zeolite topology. Constructed from u3-oxo-centered iron trimers (Fe3O) coordinated to ditopic terephthalate linkers, it combines ultra-large pore volumes with biocompatibility, low toxicity, and redox-active Fe^{3+}\/Fe^{2+} metal centers.\u003c\/p\u003e\n\u003cp\u003eFor Gas Absorption \u0026amp; Separation, the key structural features of the MIL-101(Fe) are: (1) \u003cstrong\u003eDual Mesoporous Cage Architecture\u003c\/strong\u003e: \u003cem\u003eSmall Mesoporous Cages\u003c\/em\u003e: ~ 29 Å internal diameter with pentagonal window apertures of ~ 12 Å. \u003cem\u003eLarge Mesoporous Cages\u003c\/em\u003e: ~ 34 Å internal diameter with hexagonal window apertures of ~ 16 Å. (2) \u003cstrong\u003eRedox-Active \u0026amp; Lewis Acidic Fe Centers\u003c\/strong\u003e: Thermal evacuation removes coordinated terminal water and counter-anions from the Fe3O trimers, generating coordinatively unsaturated Fe^{3+} Lewis acid sites that can be partially reduced to Fe^{2+} sites under high-vacuum activation.\u003c\/p\u003e\n\u003ctable border=\"1\" style=\"width: 100.071%; height: 257.125px;\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003ePart Number\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eCGASMOFMIL101Fe (C-GAS-MOF-MIL101Fe)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eCAS\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e1189182-67-9\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eColor\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eBrown Powder\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eAverage Sizes\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e~250-2000 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003eBET\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e\u0026gt;1000 m2\/g\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003ePore Size\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e0.3-2.0 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 71.2px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 71.2px;\"\u003e\u003cem\u003ePrimary Applications\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 71.2px;\"\u003e\n\u003cp\u003eGas absorption, storage, and separation. \u003c\/p\u003e\n\u003cp\u003eWastewater treatment, ion separation\u003c\/p\u003e\n\u003cp\u003eHeterogeneous catalysis \u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 24.675px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 24.675px;\"\u003e\u003cem\u003ePackage Grade\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 24.675px;\"\u003e5 g and 10 g\/bottle\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e\u003cb\u003e\u003cbr\u003e\u003c\/b\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cb\u003eReferences:\u003c\/b\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cb\u003e\u003c\/b\u003e\u003ca href=\"https:\/\/pubs.acs.org\/aanmf6\/article-abstract\/5\/4\/5857\/495016\/MIL-101-Fe-Networks-Supported-on-Fluorinated?redirectedFrom=fulltext\"\u003eY. Ravi, et al., MIL-101(Fe) Networks Supported on Fluorinated Graphene Nanosheets as Coatings for Oil Sorption, ACS Appl. Nano Mater. (2022) 5 (4): 5857–5867.\u003c\/a\u003e\u003ca href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S1387181123005371\"\u003e\u003c\/a\u003e\n\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S0277538716305290\"\u003eA. D.S. Barbosa, et al., Catalytic performance and electrochemical behaviour of Metal–organic frameworks: MIL-101(Fe) versus NH2-MIL-101(Fe), Polyhedron, 2017, 127, 464-470\u003c\/a\u003e\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"TYXC","offers":[{"title":"5 g","offer_id":48257719468262,"sku":"CGASMOFMIL101FeW5","price":399.0,"currency_code":"USD","in_stock":true},{"title":"10 g","offer_id":48257719501030,"sku":"CGASMOFMIL101FeW10","price":749.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CGASMOFMIL101Fe_main.jpg?v=1788031319","url":"https:\/\/echemsupplies.com\/products\/cgasmofmil101fe","provider":"EChem Supplies","version":"1.0","type":"link"}