{"product_id":"cgasmofmil68al","title":"MIL-68(Al) Metal Organic Frameworks (MOFs) Powder for Gas Absorption and Separation, CGASMOFMIL68Al","description":"\u003cp\u003eMIL-68(Al) (Al(OH)(BDC), where BDC = 1,4-benzenedicarboxylate}) is an aluminum-based metal-organic framework containing infinite 1D chains of corner-sharing AlO4(OH)2 octahedra bridged by terephthalate linkers. While sharing the identical chemical composition with the widely studied MIL-53(Al), MIL-68(Al) is a rigid structural polymorph with a Kagome-like network that features dual 1D straight channels and does not undergo framework breathing transitions.\u003c\/p\u003e\n\u003cp\u003eThe critical structural and functional features of the MIL-68(Al) are shown below: (1) \u003cstrong\u003eDual 1D Channel System (Kagome Lattice)\u003c\/strong\u003e: \u003cem\u003eLarge Hexagonal Channels\u003c\/em\u003e: Internal diameter of ~16.0–17.0 Å (accessible window ~ 14.5 Å), allowing rapid diffusion of larger gas guests and organic vapors. \u003cem\u003eSmall Triangular Channels\u003c\/em\u003e: Internal diameter of ~ 6.0–6.5 Å, offering size-selective micropores with strong confinement effects for small gas molecules. (2) \u003cstrong\u003eRigid Framework Topology\u003c\/strong\u003e: Unlike MIL-53(Al) (which flexes between narrow-pore and large-pore forms under pressure\/temperature), the connecting mode in MIL-68(Al) locks the framework in a rigid, permanently open state across all pressures and hydration levels. (3) \u003cstrong\u003eChemical, Hydrothermal \u0026amp; Thermal Stability\u003c\/strong\u003e: The Al–O coordination chains provide exceptional stability in water, humidity, and mild acidic media, with thermal stability extending up to ~ 450–500°C in air\/inert atmospheres.\u003c\/p\u003e\n\u003ctable border=\"1\" style=\"width: 100.071%; height: 257.125px;\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003ePart Number\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eCGASMOFMIL68Al (C-GAS-MOF-MIL68Al)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eCAS\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e\u003cspan\u003e1410543-01-4\u003c\/span\u003e\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eColor\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eWhite Powder\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eSize\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e200-500 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003eBET\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e~1400-1600 m2\/g\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003ePore Size\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e0.6-1.7 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 71.2px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 71.2px;\"\u003e\u003cem\u003ePrimary Applications\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 71.2px;\"\u003e\n\u003cp\u003eGas absorption, storage, and separation. \u003c\/p\u003e\n\u003cp\u003eWastewater treatment, ion separation,\u003c\/p\u003e\n\u003cp\u003eHeterogeneous catalysis \u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 24.675px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 24.675px;\"\u003e\u003cem\u003ePackage Grade\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 24.675px;\"\u003e5 g and 10 g\/bottle (a larger quantity can be supplied upon request)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e\u003cb\u003e\u003cbr\u003e\u003c\/b\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cb\u003eReferences:\u003c\/b\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cb\u003e\u003c\/b\u003e\u003ca href=\"https:\/\/pubs.rsc.org\/jm\/article-abstract\/22\/20\/10210\/373183\/Probing-the-adsorption-performance-of-the-hybrid\"\u003eQ. Yang, et al., Probing the adsorption performance of the hybrid porous MIL-68(Al): a synergic combination of experimental and modelling tools, J. Mater. Chem. (2012) 22 (20): 10210–10220.\u003c\/a\u003e\n\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"https:\/\/www.tandfonline.com\/doi\/abs\/10.1080\/00222348.2026.2669323\"\u003eZ. Liu, et al., Amino-Functionalized MIL-68(Al) and PIM-1 for Efficient CO2 Capture, Journal of Macromolecular Science, Part B, DOI: 10.1080\/00222348.2026.2669323.\u003c\/a\u003e\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"TYXC","offers":[{"title":"5 g","offer_id":48259629777126,"sku":"CGASMOFMIL68AlW5","price":199.0,"currency_code":"USD","in_stock":true},{"title":"10 g","offer_id":48259629809894,"sku":"CGASMOFMIL68AlW10","price":399.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CGASMOFMIL68Al_main.jpg?v=1788114427","url":"https:\/\/echemsupplies.com\/products\/cgasmofmil68al","provider":"EChem Supplies","version":"1.0","type":"link"}