{"product_id":"cgasmofmil88afe","title":"MIL-88A(Fe) Metal Organic Frameworks (MOFs) Powder for Gas Absorption and Separation, CGASMOFMIL88AFe","description":"\u003cp\u003eMIL-88A(Fe) (Fe3O(X)(H}2O)2(fumarate)3, where X = OH- or Cl-; fumarate = trans-butenedicarboxylate) is a flexible, iron-based metal-organic framework with an acs topology. Constructed from inorganic u3-oxo-centered iron trimers (Fe3O) cross-linked by short, linear fumaric acid linkers, it forms 1D hexagonal and bipyramidal diamond channels known for reversible \"breathing\" transitions under guest inclusion.\u003c\/p\u003e\n\u003cp\u003eFor Gas Absorption \u0026amp; Separation, the key structural features of the MIL-88A(Fe) are: (1) \u003cstrong\u003eExtreme Framework Flexibility (\"Breathing Effect\")\u003c\/strong\u003e: MIL-88A exhibits dynamic lattice expansion without bond breaking: \u003cem\u003eDried \/ Closed Form (Contracted)\u003c\/em\u003e: Unit cell volume contracts upon desolvation, with narrow pore channels (\u0026lt; 3 Å) that can appear virtually non-porous to 77 K N2. \u003cem\u003eSolvated \/ Open Form (Expanded)\u003c\/em\u003e: Guest interaction with the polar iron trimer triggers an expansion of the unit cell volume by up to ~ 85–100%, opening the hexagonal channels up to ~ 6.0–8.0 Å. (2) \u003cstrong\u003eLewis Acidic \/ Redox-Active Fe^{3+}\/Fe^{2+} Sites\u003c\/strong\u003e: Coordination-unsaturated iron sites on the Fe3O trimers provide strong electrostatic interaction and \u003cspan\u003eπ\u003c\/span\u003e-backbonding capabilities for polar and unsaturated gases. (3) \u003cstrong\u003eGreen \u0026amp; Biocompatible Composition\u003c\/strong\u003e: Built entirely from non-toxic iron and fumaric acid (an endogenous metabolic intermediate), MIL-88A provides high biocompatibility for medical gas storage\/delivery (NO, CO) and green industrial scrubbing.\u003c\/p\u003e\n\u003ctable border=\"1\" style=\"width: 100.071%; height: 292.725px;\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003ePart Number\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eCGASMOFMIL88AFe (C-GAS-MOF-MIL88AFe)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eCAS\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e1138446-56-6\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eColor\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eBrown Powder\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eAverage Sizes\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eW: 50 nm, L:50-2000 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003eBET\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e\u0026gt;100 m2\/g\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003ePore Size\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e0.4-2.0 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 106.8px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 106.8px;\"\u003e\u003cem\u003ePrimary Applications\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 106.8px;\"\u003e\n\u003cp\u003eGas absorption, storage, and separation. \u003c\/p\u003e\n\u003cp\u003eWastewater treatment, ion separation\u003c\/p\u003e\n\u003cp\u003eHeterogeneous catalysis \u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 24.675px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 24.675px;\"\u003e\u003cem\u003ePackage Grade\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 24.675px;\"\u003e5 g, 10 g, and 20 g\/bottle\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e\u003cb\u003e\u003cbr\u003e\u003c\/b\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cb\u003eReferences:\u003c\/b\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cb\u003e\u003c\/b\u003e\u003ca href=\"https:\/\/pubs.acs.org\/cmatex\/article-abstract\/25\/3\/479\/785945\/Impact-of-the-Flexible-Character-of-MIL-88-Iron?redirectedFrom=fulltext\"\u003eN. A. Ramsahye, et al., Impact of the Flexible Character of MIL-88 Iron(III) Dicarboxylates on the Adsorption of n‑Alkanes, Chem. Mater. (2013) 25 (3): 479–488.\u003c\/a\u003e\u003ca href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S1387181123005371\"\u003e\u003c\/a\u003e\n\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"https:\/\/pubs.acs.org\/cmatex\/article-abstract\/25\/9\/1592\/786597\/Nitric-Oxide-Adsorption-and-Delivery-in-Flexible?redirectedFrom=fulltext\"\u003eA. C. McKinlay, et al., Nitric Oxide Adsorption and Delivery in Flexible MIL-88(Fe) Metal–Organic Frameworks, Chem. Mater. (2013) 25 (9): 1592–1599.\u003c\/a\u003e\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"TYXC","offers":[{"title":"5 g","offer_id":48257900773606,"sku":"CGASMOFMIL88AFeW5","price":219.0,"currency_code":"USD","in_stock":true},{"title":"10 g","offer_id":48257900806374,"sku":"CGASMOFMIL88AFeW10","price":399.0,"currency_code":"USD","in_stock":true},{"title":"20 g","offer_id":48257900839142,"sku":"CGASMOFMIL88AFeW20","price":749.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CGASMOFMIL88AFe_main.jpg?v=1788035283","url":"https:\/\/echemsupplies.com\/products\/cgasmofmil88afe","provider":"EChem Supplies","version":"1.0","type":"link"}