{"product_id":"cgasmofuio66zr","title":"UIO-66(Zr) Metal Organic Frameworks (MOFs) Powder for Gas Absorption and Separation, CGASMOFUIO66Zr","description":"\u003cp\u003eUiO-66 (Universitetet i Oslo-66, Zr6O4(OH)4(BDC)6, where BDC = 1,4-benzenedicarboxylate) is a benchmark zirconium-based metal-organic framework (MOF). Its framework is constructed from 12-connected hexanuclear zirconium oxo-clusters (Zr6O4(OH)4) coordinated to 12 terephthalate linkers in a face-centered cubic (fcu) topology, endowing it with some of the highest chemical, thermal, and mechanical stabilities known in MOF chemistry.\u003c\/p\u003e\n\u003cp\u003eThe key structural features of the UIO-66 are: (1) \u003cstrong\u003eDual-Cage Architecture \u0026amp; Pore Apertures\u003c\/strong\u003e: \u003cem\u003eOctahedral Cages\u003c\/em\u003e: Central diameter of ~ 11 Å; Tetrahedral Cages: Central diameter of ~ 8 Å; \u003cem\u003eTriangular Window Apertures\u003c\/em\u003e: Pore openings of ~ 6.0 Å, facilitating molecular diffusion of small gas molecules while providing size-selective exclusion pathways. (2) \u003cstrong\u003eExceptional Stability Matrix\u003c\/strong\u003e: T\u003cem\u003ehermal Stability\u003c\/em\u003e: Stable up to ~ 450–500°C in air\/inert environments due to strong Zr(IV)–O ionic\/covalent coordination bonds. \u003cem\u003eAqueous \u0026amp; Acidic Stability\u003c\/em\u003e: Highly resistant to boiling water, high-humidity gas streams, and acidic media (pH=1–9), avoiding the structural collapse common to Cu- or Zn-based frameworks. \u003cem\u003eMechanical Resilience\u003c\/em\u003e: Can withstand pelletization and hydrostatic compaction pressures up to several thousand bar without loss of crystallinity. (3) \u003cstrong\u003eTextural Properties\u003c\/strong\u003e: \u003cem\u003eBET Surface Area\u003c\/em\u003e: Typically 1100–1500 m2\/g (pristine\/ideal framework). \u003cem\u003ePore Volume\u003c\/em\u003e: 0.45–0.55 cm3\/g (increases with defect engineering).\u003c\/p\u003e\n\u003ctable border=\"1\" style=\"width: 100.071%; height: 257.125px;\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003ePart Number\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eCGASMOFUIO66Zr (C-GAS-MOF-UIO66Zr)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eCAS\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e1072413-89-8\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eColor\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eWhite Powder\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eAverage Sizes\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e50-100 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003eBET\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e\u0026gt;1000 m2\/g\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003ePore Size\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e0.3-1.1 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 71.2px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 71.2px;\"\u003e\u003cem\u003ePrimary Applications\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 71.2px;\"\u003e\n\u003cp\u003eGas absorption, storage, and separation. \u003c\/p\u003e\n\u003cp\u003eWastewater treatment, ion separation, \u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 24.675px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 24.675px;\"\u003e\u003cem\u003ePackage Grade\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 24.675px;\"\u003e5 g, 10 g, and 20 g\/bottle\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e\u003cb\u003e\u003cbr\u003e\u003c\/b\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cb\u003eReferences:\u003c\/b\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cb\u003e\u003c\/b\u003e\u003ca href=\"https:\/\/pubs.acs.org\/aamick\/article-abstract\/9\/44\/38919\/705723\/Chemically-Cross-Linked-MOF-Membrane-Generated?redirectedFrom=fulltext\"\u003eB. J. Yao, et al., Chemically Cross-Linked MOF Membrane Generated from Imidazolium-Based Ionic Liquid-Decorated UiO-66 Type NMOF and Its Application toward CO2 Separation and Conversion, ACS Appl. Mater. Interfaces (2017) 9 (44): 38919–38930.\u003c\/a\u003e\n\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"https:\/\/pubs.acs.org\/aamick\/article-abstract\/9\/14\/12878\/702795\/Metal-Organic-Framework-UiO-66-Layer-A-Highly\"\u003eS. Friebe, et al., Metal–Organic Framework UiO-66 Layer: A Highly Oriented Membrane with Good Selectivity and Hydrogen Permeance, ACS Appl. Mater. Interfaces (2017) 9 (14): 12878–12885.\u003c\/a\u003e\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"TYXC","offers":[{"title":"5 g","offer_id":48250427605222,"sku":"CGASMOFUIO66ZrW5","price":219.0,"currency_code":"USD","in_stock":true},{"title":"10 g","offer_id":48250427637990,"sku":"CGASMOFUIO66ZrW10","price":399.0,"currency_code":"USD","in_stock":true},{"title":"20 g","offer_id":48250427670758,"sku":"CGASMOFUIO66ZrW20","price":749.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CGASMOFUIO66Zr_main.jpg?v=1787935814","url":"https:\/\/echemsupplies.com\/products\/cgasmofuio66zr","provider":"EChem Supplies","version":"1.0","type":"link"}