{"product_id":"cgasmofuio67zr","title":"UIO-67(Zr) Metal Organic Frameworks (MOFs) Powder for Gas Absorption and Separation, CGASMOFUIO67Zr","description":"\u003cp\u003eUiO-67(Zr) (Zr6O4(OH)4(BPDC)6, where BPDC = biphenyl-4,4'-dicarboxylate) is the isoreticular, expanded-pore analogue of UiO-66. Featuring the same 12-connected face-centered cubic (fcu topology), it incorporates elongated biphenyl linkers between the hexanuclear zirconium oxo-clusters (Zr6O4(OH)4), expanding both cage volumes and aperture diameters.\u003c\/p\u003e\n\u003cp\u003eFor Gas Absorption \u0026amp; Separation, the key structural and functional features of the UIO-67(Zr) are: (1) \u003cstrong\u003eExpanded Dual-Cage Microporous Network\u003c\/strong\u003e: \u003cem\u003eOctahedral Cages\u003c\/em\u003e: Free internal diameter of ~ 18–21.5 \u003cspan\u003eÅ \u003c\/span\u003e(compared to 11 \u003cspan\u003eÅ\u003c\/span\u003e in pristine UiO-66). \u003cem\u003eTetrahedral Cages\u003c\/em\u003e: Free internal diameter of ~ 11.5–12.0 \u003cspan\u003eÅ\u003c\/span\u003e. \u003cem\u003eTriangular Window Apertures:\u003c\/em\u003e\u003cspan class=\"\"\u003e Opneing of \u003c\/span\u003e\u003cspan\u003e\u003cspan class=\"math-inline\"\u003e~ 8.0–10.0 Å\u003c\/span\u003e\u003c\/span\u003e\u003cspan class=\"\"\u003e allowing rapid mass transport of larger gases, bulky aromatics, and organometallic complexes\u003c\/span\u003e\u003cspan class=\"\"\u003e.\u003c\/span\u003e (2) \u003cstrong\u003eHydrothermal \u0026amp; Thermal Stability\u003c\/strong\u003e: Retains the strong Zr(IV)–O coordination bond, remaining thermally stable up to ~ 450–500°C in inert atmosphere. While more water-stable than Cu- or Zn-based MOFs, its extended linkers make it slightly more susceptible to capillary-force collapse during solvent evacuation than UiO-66.\u003c\/p\u003e\n\u003ctable border=\"1\" style=\"width: 100.071%; height: 292.725px;\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003ePart Number\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eCGASMOFUIO67Zr (C-GAS-MOF-UIO67Zr)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eCAS\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e1072413-83-2\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eColor\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eWhite Powder\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eAverage Sizes\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e50-300 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003eBET\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e~1800-2500 m2\/g\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003ePore Size\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e1.2-2.3 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 106.8px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 106.8px;\"\u003e\u003cem\u003ePrimary Applications\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 106.8px;\"\u003e\n\u003cp\u003eGas absorption, storage, and separation. \u003c\/p\u003e\n\u003cp\u003eWastewater treatment, ion separation\u003c\/p\u003e\n\u003cp\u003eHeterogeneous catalysis \u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 24.675px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 24.675px;\"\u003e\u003cem\u003ePackage Grade\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 24.675px;\"\u003e5 g and 10 g\/bottle (large quantity can be supplied upon request)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e\u003cb\u003e\u003cbr\u003e\u003c\/b\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cb\u003eReferences:\u003c\/b\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cb\u003e\u003c\/b\u003e\u003ca href=\"https:\/\/pubs.acs.org\/iecred\/article-abstract\/56\/30\/8689\/1568150\/Selective-Adsorption-Performances-of-UiO-67-for?redirectedFrom=fulltext\"\u003eY. Zhang, et al., Selective Adsorption Performances of UiO-67 for Separation of Light Hydrocarbons C1, C2, and C3, Ind. Eng. Chem. Res. (2017) 56 (30): 8689–8696.\u003c\/a\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003ca href=\"https:\/\/pubs.acs.org\/cmatex\/article-abstract\/29\/7\/3111\/1458525\/Azobenzene-Guest-Molecules-as-Light-Switchable-CO2?redirectedFrom=fulltext\"\u003eA. Knebel, et al., Azobenzene Guest Molecules as Light-Switchable CO2 Valves in an Ultrathin UiO-67 Membrane, \u003cem\u003eChem. Mater.\u003c\/em\u003e\u003c\/a\u003e\u003cspan\u003e\u003ca href=\"https:\/\/pubs.acs.org\/cmatex\/article-abstract\/29\/7\/3111\/1458525\/Azobenzene-Guest-Molecules-as-Light-Switchable-CO2?redirectedFrom=fulltext\"\u003e (2017) 29 (7): 3111–3117.\u003c\/a\u003e\u003c\/span\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"TYXC","offers":[{"title":"5 g","offer_id":48259616932070,"sku":"CGASMOFUIO67ZrW5","price":229.0,"currency_code":"USD","in_stock":true},{"title":"10 g","offer_id":48259616964838,"sku":"CGASMOFUIO67ZrW10","price":399.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CGASMOFUIO67Zr_main.jpg?v=1788112360","url":"https:\/\/echemsupplies.com\/products\/cgasmofuio67zr","provider":"EChem Supplies","version":"1.0","type":"link"}