{"product_id":"cgaspcmofmil68nh2al","title":"MIL-68-NH2(Al) Metal Organic Frameworks (MOFs) Powder for Gas Absorption, Separation, and Photocatalysis, CGASPCMOFMIL68NH2Al","description":"\u003cp\u003eNH2-MIL-68(Al) (or MIL-68-NH2(Al), chemical formula Al(OH)(BDC-NH2), where BDC-NH2 = 2-amino-1,4-benzenedicarboxylate) is the isoreticular, amino-functionalized analogue of pristine MIL-68(Al). It is constructed from infinite 1D chains of corner-sharing AlO4(OH)2 octahedra bridged by 2-aminoterephthalate linkers, forming a rigid Kagome-like topology with dual 1D straight channels that exhibit no framework breathing transitions.\u003c\/p\u003e\n\u003cp\u003eThe critical structural and functional features of the MIL-68(Al) are shown below: (1) \u003cstrong\u003eDual 1D Channel System (Kagome Lattice)\u003c\/strong\u003e: \u003cem\u003eLarge Hexagonal Channels\u003c\/em\u003e: Internal diameter of ~15.0–16.5 Å (accessible window ~ 14.5 Å), allowing rapid diffusion of larger gas guests and organic vapors. \u003cem\u003eSmall Triangular Channels\u003c\/em\u003e: Internal diameter of ~ 5.0–6.0 Å, offering size-selective micropores with strong confinement effects for small gas molecules. (2) \u003cstrong\u003eLewis Basic \u0026amp; Polar Pore Environment\u003c\/strong\u003e: Uncoordinated aromatic -NH2 groups directly decorate the 1D pore walls, introducing electron-rich nitrogen lone pairs and hydrogen-bonding sites that selectively interact with acidic and polar guest molecules. (3) \u003cstrong\u003eHydrothermal \u0026amp; Chemical Stability\u003c\/strong\u003e: Strong covalent\/ionic Al(III)–O coordination bonds provide resilience in water, high relative humidity, and mild acidic\/basic environments, with thermal stability up to ~ 320–360°C.\u003c\/p\u003e\n\u003ctable border=\"1\" style=\"width: 100.071%; height: 257.125px;\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003ePart Number\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eCGASPCMOFMIL68NH2Al (C-GASPC-MOF-MIL68NH2Al)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eCAS\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e\u003cspan\u003e1410543-02-5\u003c\/span\u003e\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eColor\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003eBrown Powder\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003eSize\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e200-500 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003eBET\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e~950-1250 m2\/g\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.875px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 26.875px;\"\u003e\u003cem\u003ePore Size\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 26.875px;\"\u003e0.6-1.7 nm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 71.2px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 71.2px;\"\u003e\u003cem\u003ePrimary Applications\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 71.2px;\"\u003e\n\u003cp\u003eGas absorption, storage, and separation. \u003c\/p\u003e\n\u003cp\u003eWastewater treatment, ion separation,\u003c\/p\u003e\n\u003cp\u003ePhotocatalysis \u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 24.675px;\"\u003e\n\u003ctd style=\"width: 24.6929%; height: 24.675px;\"\u003e\u003cem\u003ePackage Grade\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 72.8334%; height: 24.675px;\"\u003e5 g\/bottle (a larger quantity can be supplied upon request)\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e\u003cb\u003e\u003cbr\u003e\u003c\/b\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cb\u003eReferences:\u003c\/b\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\n\u003cb\u003e\u003c\/b\u003e\u003ca href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S0925838825016810\"\u003eQ. Sun, et al., New insights on how metal clusters in MIL-68-NH2 influence the photocatalytic nitrogen fixation, Journal of Alloys and Compounds, 2025, 1023, 180123.\u003c\/a\u003e\n\u003c\/li\u003e\n\u003cli\u003e\n\u003ca href=\"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/abs\/10.1002\/adfm.202101335\"\u003eY. Lu, et al., Emerging Homochiral Porous Materials for Enantiomer Separation, Adv Funct. Mater., 2021, 31, \u003c\/a\u003e\u003cspan\u003e\u003ca href=\"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/abs\/10.1002\/adfm.202101335\"\u003e2101335\u003c\/a\u003e\u003c\/span\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"TYXC","offers":[{"title":"Default Title","offer_id":48259731325158,"sku":"CGASPCMOFMIL68NH2Al","price":399.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CGASPCMOFMIL68NH2Al_main.jpg?v=1788120233","url":"https:\/\/echemsupplies.com\/products\/cgaspcmofmil68nh2al","provider":"EChem Supplies","version":"1.0","type":"link"}