{"product_id":"clibclmfp73","title":"LiMn0.7Fe0.3PO4 (LMFP73) Powder for Li-Ion Battery Cathode, 100-500 g\/bottle, CLIBCLMFP73","description":"\u003cp\u003eLiMn0.7Fe0.3PO4 (LMFP73) is a high-performance, manganese-rich olivine-structured cathode material for lithium-ion batteries. It represents a major evolutionary step over standard lithium iron phosphate (LiFePO4, or LFP) by doping a high fraction of manganese (Mn) into the iron (Fe) lattice sites to significantly boost energy density.\u003c\/p\u003e\n\u003cp\u003eLMFP73 crystallizes in the same orthorhombic olivine structure (space group Pnma) as LFP. The framework consists of corner-sharing [MnO6] and [FeO6] octahedra bridged by tetrahedral [PO4]^{3-} polyanions. Because it contains two distinct transition metal ions, its discharge curve features a characteristic dual-voltage plateau: (1) \u003cstrong\u003eMn Region (~ 4.1 V vs. Li\/Li+)\u003c\/strong\u003e: Accounts for 70% of the capacity via the Mn^{2+}\/ {Mn}^{3+} redox couple. This high-voltage operation is what elevates the energy density of LMFP73 by ~15–20% over standard LFP, pushing it closer to NCM523 architectures while retaining polyanionic safety. (2) \u003cstrong\u003eFe Region (~3.5 V vs. Li\/Li+)\u003c\/strong\u003e: Accounts for 30% of the capacity via the Fe^{2+}\/Fe^{3+} redox couple. This plateau provides a highly reliable state-of-charge (SOC) marker for battery management systems (BMS).\u003c\/p\u003e\n\u003cp\u003eIntroducing 30% iron Fe^(2+) acts as a structural buffer. The highly stable, non-distorting [FeO6] octahedra absorb the mechanical stresses generated by the neighboring [MnO6] units. This synergy reduces the overall volume change during cycling to acceptable levels, suppressing phase separation and facilitating rapid Li+ transport along the 1D [010] channels.\u003c\/p\u003e\n\u003ctable width=\"100%\" style=\"width: 100%; height: 286.812px;\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 41.95px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 41.95px;\"\u003e\u003cem\u003ePart Number\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 41.95px;\"\u003e\n\u003cp\u003e\u003cspan\u003eCLIBCLMFP73 (C-LIB-C-LMFP73)\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 55.2px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 55.2px;\"\u003e\u003cem\u003eChemical Composition\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 55.2px;\"\u003e\n\u003cp\u003e\u003cspan\u003eLi: 4.58 wt%,  Mn: 22.78 wt%,  Fe: 11.00 wt%,  P: 19.02 wt%, \u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 38.375px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 38.375px;\"\u003e\n\u003cstrong\u003e \u003c\/strong\u003e\u003cem\u003eParticle Size Distribution\u003c\/em\u003e\n\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 38.375px;\"\u003e\n\u003cp\u003e\u003cspan\u003eD10 = 0.29 um;  \u003c\/span\u003e\u003cspan\u003eD50 = 1.06 um;   D90 = 14.75 um\u003c\/span\u003e\u003cspan\u003e\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 23.3625px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 23.3625px;\"\u003e\u003cem\u003eTap Density\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 23.3625px;\"\u003e\u003cspan\u003e0.89 g\/cm3\u003c\/span\u003e\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 23.3625px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 23.3625px;\"\u003e\u003cem\u003eSpecific Area\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 23.3625px;\"\u003e15.51 m2\/g\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 23.3625px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 23.3625px;\"\u003e\u003cem\u003eWater Level\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 23.3625px;\"\u003e\u0026lt;529 ppm\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 10px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 10px;\"\u003e\u003cem\u003eFirst Discharging Capacity\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 10px;\"\u003e\n\u003cp\u003e~145.68 mAh\/g (0.1 C)\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 35.6px;\"\u003e\u003cem\u003eFirst Columbic Efficiency\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 35.6px;\"\u003e\n\u003cp\u003e95.54% \u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 35.6px;\"\u003e\u003cem\u003ePackage Grade\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 35.6px;\"\u003e\n\u003cp\u003e100 g, 200 g, and 500 g\/bottle\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e \u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eNotes\u003c\/strong\u003e: (1) Please store the LMFP73 powder in a dry area (glovebox is preferred); \u003c\/span\u003e\u003cspan\u003e(2) The battery powder is highly recommended to be dried at 80-100°C in a vacuum oven for 6-12 h before use. \u003c\/span\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eReferences\u003c\/strong\u003e: \u003c\/span\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\u003ca href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S2211285524001708\"\u003e\u003cspan\u003eQ. Hu, et al. Revealing the voltage decay of LiMn0.7Fe0.3PO4 cathodes over cycling, Nano Energy, 2024, 123, 109422.\u003c\/span\u003e\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full\/10.1002\/celc.202400440\"\u003e\u003cspan\u003eH. Xiong, et al. A Uniform Conductive Carbon Coating of Nitrogen-Doped Carbon Improves the Electrochemical Performance of LiMn0.7Fe0.3PO4 Cathode Material for Lithium-ion Batteries, ChemElectroChem, 2024, 11, e202400440 \u003c\/span\u003e\u003c\/a\u003e\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"DCCL","offers":[{"title":"100 g","offer_id":47906547728614,"sku":"CLIBCLMFP73W100","price":79.0,"currency_code":"USD","in_stock":true},{"title":"200 g","offer_id":47906547761382,"sku":"CLIBCLMFP73W200","price":149.0,"currency_code":"USD","in_stock":true},{"title":"500 g","offer_id":47906547794150,"sku":"CLIBCLMFP73W500","price":269.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CLIBCLMFP73_main.png?v=1782018487","url":"https:\/\/echemsupplies.com\/products\/clibclmfp73","provider":"EChem Supplies","version":"1.0","type":"link"}