{"product_id":"cliblelbf","title":"1.0 M LiBF4 in Regular Solvents with Additives as Liquid Electrolyte for Lithium-Ion Battery, 50 g\/bottle, CLIBLELBF","description":"\u003cp\u003eLiBF4 (Lithium Tetrafluoroborate) is an alternative electrolyte salt used in non-aqueous electrolytes for lithium-ion batteries (LIBs), often as a co-salt with the dominant LiPF6 to mitigate the latter's drawbacks. Due to its high thermal stability and superior performance at high temperatures and in the presence of trace moisture, LiBF4 is strategically used in the following ways: \u003c\/p\u003e\n\u003cp\u003eHigh-Voltage Cathodes: LiBF4 is effective at forming a robust CEI on the positive electrode (cathode). This protection layer suppresses oxidative decomposition of the electrolyte at high operating potentials (typically \u0026gt;4.3 V), thereby enhancing the battery's cycle life and reducing impedance growth.\u003c\/p\u003e\n\u003cp\u003eWide\/Low-Temperature Electrolytes: Its good performance at sub-zero temperatures makes it a key component in electrolytes designed for applications that require a wide operating temperature range.\u003c\/p\u003e\n\u003cp\u003eCo-Salt Blends (The Synergistic Effect): LiBF4 is most often used as an additive or co-salt alongside LiPF6 (e.g. 1:1 molar ratio). This blend takes advantage of the best features of both salts: (a) LiPF6 ensures high ionic conductivity and forms the necessary SEI on the anode; (b) LiBF4 ensures thermal stability and forms the protective CEI on the cathode.\u003c\/p\u003e\n\u003ctable style=\"width: 100%; height: 178.6px;\" width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 35.6px;\"\u003e\u003cem\u003ePart Number\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003eCLIBLELBF (C-LIB-LE-LBF)\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 35.6px;\"\u003e\u003cem\u003eAppearance\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003eColorless Liquid\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr\u003e\n\u003ctd style=\"width: 33.6331%;\"\u003e\u003cem\u003eElectrolyte Composition\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%;\"\u003e\n\u003cp\u003e\u003cspan\u003e1.0 M LiPF6 in EC\/DMC\/DEC\/EMC with\/without additives\u003c\/span\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e(\u003cspan style=\"color: rgb(255, 42, 0);\"\u003eCustomized electrolyte formula can be provided upon request\u003c\/span\u003e)\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 16.6px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 16.6px;\"\u003e\u003cem\u003ePackage Size\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 16.6px;\"\u003e\u003cspan\u003e50 g\/bottle\u003c\/span\u003e\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e \u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eNotes\u003c\/strong\u003e: Please store the LiBF4 liquid electrolyte in the glovebox due to its sensitivity to humidity.\u003c\/span\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eReferences\u003c\/strong\u003e: \u003c\/span\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\u003cspan\u003e\u003ca href=\"https:\/\/iopscience.iop.org\/article\/10.1149\/1.1466857\/meta\"\u003eS. S. Zhang, et al. Study of LiBF4 as an Electrolyte Salt for a Li-Ion Battery, 2002,149,  A586\u003c\/a\u003e.\u003c\/span\u003e\u003c\/li\u003e\n\u003cli\u003e\n\u003cspan\u003e\u003ca href=\"https:\/\/link.springer.com\/article\/10.1007\/s10008-002-0300-9\"\u003eS. Zhang, et al. Low-temperature performance of Li-ion cells with a LiBF4-based electrolyte, J. Solid State Electrochem., 2003, 7, 147-151\u003c\/a\u003e. \u003c\/span\u003e\u003cbr\u003e\n\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"KLD","offers":[{"title":"1.0 M LiBF4 in FEC : DEC = 1:1","offer_id":47015080100070,"sku":"CLIBLELBFFEDE11","price":139.0,"currency_code":"USD","in_stock":false},{"title":"1.0 M LiBF4 in EC: DEC = 1:1","offer_id":47015080132838,"sku":"CLIBLELBFEDE11","price":139.0,"currency_code":"USD","in_stock":false},{"title":"1.0 M LiBF4 in EC : DEC = 1:1 with 5% FEC","offer_id":47015080231142,"sku":"CLIBLELBFEDE11F5","price":139.0,"currency_code":"USD","in_stock":false},{"title":"1.0 M LiBF4 in EC: DEC = 1:1 with 1% VC + 10% FEC","offer_id":47015080165606,"sku":"CLIBLELBFEDE11V1F10","price":139.0,"currency_code":"USD","in_stock":false},{"title":"1.0 M LiBF4 in EC: EMC =3:7","offer_id":47015080198374,"sku":"CLIBLELBFEEM37","price":139.0,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CLIBLELBF.png?v=1765005829","url":"https:\/\/echemsupplies.com\/products\/cliblelbf","provider":"EChem Supplies","version":"1.0","type":"link"}