{"product_id":"clibsselzac","title":"LZAC (Li2.25Zr0.75Al0.25Cl6) Powder as Solid-State Electrolyte for Lithium-Ion Battery, 10-50 g\/bottle, CLIBSSELZAC","description":"\u003cp\u003eThe Li-Zr-Al-Cl (Lithium Zirconium Aluminum Chloride) system represents an exciting frontier in Halide Solid-State Electrolytes (HSSEs). Historically, halide research heavily relied on rare-earth or expensive transition metals like Indium (LiInCl6), Yttrium (Li3YCl6), or Scandium (Li3ScCl6). The {Li-Zr-Al-Cl} framework strips out these cost bottlenecks by leveraging earth-abundant, low-cost central cations (Zr^{4+} and Al^{3+}), rendering it highly attractive for commercially scalable all-solid-state batteries (ASSBs).\u003c\/p\u003e\n\u003cp\u003eWhen substituting Al^{3+} into the LZC lattice (forming compositions like Li2.25Zr0.75Al0.25Cl6) or introducing Zr^{4+} into a LAC lattice, a heterovalent cation mismatch is created. This structural manipulation yields two profound effects: (1) \u003cstrong\u003eVacancy Creation \u0026amp; Lattice Distortions\u003c\/strong\u003e: The discrepancy in ionic radii and charge numbers between Zr^{4+} and Al^{3+} creates localized structural disorder, broadening the interstitial bottlenecks through which Li+ must pass. (2) \u003cstrong\u003eLong-Range Cooperative Transport\u003c\/strong\u003e: The doping shortens the nearest-neighbor Li-Li hopping distances. This shifts the transport mechanics from an isolated, high-activation-energy jump to a continuous, long-range cooperative migration network, pushing room-temperature ionic conductivity firmly into the 10^{-3} S\/cm superionic conductor threshold.\u003c\/p\u003e\n\u003ctable width=\"100%\" style=\"width: 100%; height: 648.4px;\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 36.6px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 36.6px;\"\u003e\u003cem\u003ePart Number\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 36.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003eCLIBSSELZAC (C-LIB-SSE-LZAC)\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 35.6px;\"\u003e\u003cem\u003eChemical Formula\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 35.6px;\"\u003e\n\u003cp\u003eLi2.25Zr0.75Al0.25Cl6 (The Li2.8Zr0.75Al0.25CI3.75O1.4 also can be supplied upon request)\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 35.6px;\"\u003e\u003cem\u003eAppearance\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003eWhite Powder\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 35.6px;\"\u003e\u003cem\u003eSize Distribution\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003eD50= ~5.0 um\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 145.4px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 145.4px;\"\u003e\u003cem\u003eXRD\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 145.4px;\"\u003e\n\u003cdiv style=\"text-align: start;\"\u003e\u003cimg style=\"margin-bottom: 16px; float: none;\" src=\"https:\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CLIBSSELZAC_XRD_160x160.jpg?v=1783052374\"\u003e\u003c\/div\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 201px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 201px;\"\u003e\u003cem\u003eIonic Conductivity\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 201px;\"\u003e\n\u003cp\u003e\u003cspan\u003e\u0026gt;1.13 x10-3 S\/cm at 25 °C \u003c\/span\u003e\u003c\/p\u003e\n\u003cdiv style=\"text-align: start;\"\u003e\u003cimg src=\"https:\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CLIBSSELZAC_Conductivity_160x160.jpg?v=1783052374\" style=\"margin-bottom: 16px; float: none;\"\u003e\u003c\/div\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 139px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 139px;\"\u003e\u003cem\u003eCell Performance\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 139px;\"\u003e\n\u003cp\u003e\u003cspan\u003eSpecific Capacity: 168 mAh\/g (0.1 C, 25 °C)\u003c\/span\u003e\u003c\/p\u003e\n\u003cdiv style=\"text-align: start;\"\u003e  \u003cimg src=\"https:\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CLIBSSELZAC_Charge-Discharge_160x160.jpg?v=1783052374\" style=\"margin-bottom: 16px; float: none;\"\u003e \u003cimg src=\"https:\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CLIBSSELZAC_Rating_160x160.jpg?v=1783052374\" style=\"margin-bottom: 16px; float: none;\"\u003e\n\u003c\/div\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 19.6px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 19.6px;\"\u003e\u003cem\u003ePackage Size\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 19.6px;\"\u003e10 g, 20 g, and 50 g\/bottle\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e \u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eNotes\u003c\/strong\u003e: Please try to store the LZAC powders in a dry place (glovebox is preferred)\u003c\/span\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eReferences\u003c\/strong\u003e: \u003c\/span\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\u003ca href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S240582972400271X\"\u003e\u003cspan\u003eK. N. Gao, et al. Aliovalent substitution of Al3+ in Li2ZrCl6 solid electrolyte towards large-scale application, Energy Storage Materials, 2024, 70, 103444\u003c\/span\u003e\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003cspan\u003e\u003ca href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S2352152X24046036\"\u003eY. Wu, et al. Innovative doping strategies for Li2ZrCl6 solid electrolytes: A first-principles approach, Journal of Energy Storage, 2025, 107, 115017\u003c\/a\u003e \u003c\/span\u003e\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"QGTLHW","offers":[{"title":"10 g","offer_id":47944052768998,"sku":"CLIBSSELZAC10","price":149.0,"currency_code":"USD","in_stock":true},{"title":"20 g","offer_id":47944052801766,"sku":"CLIBSSELZAC20","price":259.0,"currency_code":"USD","in_stock":true},{"title":"50 g","offer_id":47944130068710,"sku":"CLIBSSELZAC50","price":599.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CLIBSSELZAC_main.jpg?v=1783051819","url":"https:\/\/echemsupplies.com\/products\/clibsselzac","provider":"EChem Supplies","version":"1.0","type":"link"}