{"product_id":"clibsselzco","title":"LZCO (Li1.75ZrCl4.75O0.5) Powder as Solid-State Electrolyte for Lithium-Ion Battery, 10-50 g\/bottle, CLIBSSELZCO","description":"\u003cp\u003eThe Li-Zr-Cl-O (Lithium Zirconium Oxychloride or LZCO) system represents a major evolutionary step in the field of Halide Solid-State Electrolytes (HSSEs). While pristine zirconium halides like Li2ZrCl6 (LZC) gained attention due to the extreme earth abundance and low cost of zirconium (~ 6 $\/kg), their practical application was severely bottlenecked by low room-temperature ionic conductivity (~10^{-5} S\/cm to 10^{-4} S\/cm). By partially substituting chlorine (Cl-) with oxygen (O}^{2-}), researchers unlocked a class of mixed-anion oxychloride superionic conductors that dramatically improve lithium-ion kinetics.\u003c\/p\u003e\n\u003cp\u003eThe inclusion of oxygen into the halide lattice completely alters the crystal structure and energy landscape for Li+ transport: (1) \u003cstrong\u003ePhase Transition \u0026amp; Disorder\u003c\/strong\u003e: Introducing the smaller, higher-valence oxide ion (O^{2-}) for Cl- induces severe lattice distortions or drives a phase transition (such as transitioning into a monoclinic structure like Li6ZrCl6O2). This structural perturbation opens up the coordination bottlenecks. (2) \u003cstrong\u003eAmorphization\u003c\/strong\u003e: At higher oxygen doping thresholds or when synthesized via high-energy ball milling, the coupled cation-anion mismatch breaks down long-range crystalline symmetry entirely. The resulting amorphous oxychloride network offers isotropic ion conduction paths, eliminating grain-boundary resistances. (3) \u003cstrong\u003eVacancy Generation\u003c\/strong\u003e: Because O^{2-} has a higher negative charge than Cl-, its incorporation allows for the structural manipulation of Li+ concentration and vacancies, lowering the migration activation energy (0.25 eV) and accelerating long-range cooperative ion hopping.\u003c\/p\u003e\n\u003ctable width=\"100%\" style=\"width: 100%; height: 688px;\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 36.6px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 36.6px;\"\u003e\u003cem\u003ePart Number\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 36.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003eCLIBSSELZCO (C-LIB-SSE-LZCO)\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 55.2px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 55.2px;\"\u003e\u003cem\u003eChemical Formula\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 55.2px;\"\u003e\n\u003cp\u003eLi1.75ZrCl4.75O0.5 (The Li2.8Zr0.75Al0.25CI3.75O1.4 also can be supplied upon request)\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 35.6px;\"\u003e\u003cem\u003eAppearance\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003eWhite Powder\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 35.6px;\"\u003e\u003cem\u003eSize Distribution\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003eD50= ~5.0 um\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 165.4px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 165.4px;\"\u003e\u003cem\u003eXRD\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 165.4px;\"\u003e\n\u003cdiv style=\"text-align: start;\"\u003e\u003cimg style=\"margin-bottom: 16px; float: none;\" src=\"https:\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CLIBSSELZCO_XRD_160x160.jpg?v=1783061056\"\u003e\u003c\/div\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 173px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 173px;\"\u003e\u003cem\u003eIonic Conductivity\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 173px;\"\u003e\n\u003cp\u003e\u003cspan\u003e~2.42 x10-3 S\/cm at 25 °C \u003c\/span\u003e\u003c\/p\u003e\n\u003cdiv style=\"text-align: start;\"\u003e\u003cimg style=\"margin-bottom: 16px; float: none;\" src=\"https:\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CLIBSSELZCO_Conductivity_160x160.jpg?v=1783061056\"\u003e\u003c\/div\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 167px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 167px;\"\u003e\u003cem\u003eCell Performance\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 167px;\"\u003e\n\u003cp\u003e\u003cspan\u003eSpecific Capacity: 168 mAh\/g (0.1 C, 25 °C)\u003c\/span\u003e\u003c\/p\u003e\n\u003cdiv style=\"text-align: start;\"\u003e  \u003cimg src=\"https:\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CLIBSSELZCO_Performance_Test_240x240.jpg?v=1783061056\" style=\"margin-bottom: 16px; float: none;\"\u003e \u003c\/div\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 19.6px;\"\u003e\n\u003ctd style=\"width: 28.0576%; height: 19.6px;\"\u003e\u003cem\u003ePackage Size\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 71.5827%; height: 19.6px;\"\u003e10, 20, and 50 g\/bottle\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e \u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eNotes\u003c\/strong\u003e: Please try to store the LZCO powders in a dry place (glovebox is preferred)\u003c\/span\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eReferences\u003c\/strong\u003e: \u003c\/span\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\u003ca href=\"https:\/\/www.nature.com\/articles\/s41467-025-65702-2\"\u003e\u003cspan\u003eJ. S. Kim, et al. Divalent anion-driven framework regulation in Zr-based halide solid electrolytes for all-solid-state batteries, Nature Communications, 2025, 16, 10678\u003c\/span\u003e\u003c\/a\u003e\u003c\/li\u003e\n\u003cli\u003e\u003cspan\u003e\u003ca href=\"https:\/\/www.nature.com\/articles\/s41524-024-01346-y\"\u003eF. Hussain, et al. Exploring superionic conduction in lithium oxyhalide solid electrolytes considering composition and structural factors, npj Computational Materials, 2024, 10, 148\u003c\/a\u003e \u003c\/span\u003e\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"QGTLHW","offers":[{"title":"10 g","offer_id":47944054964454,"sku":"CLIBSSELZCO10","price":149.0,"currency_code":"USD","in_stock":true},{"title":"20 g","offer_id":47944054997222,"sku":"CLIBSSELZCO20","price":259.0,"currency_code":"USD","in_stock":true},{"title":"50 g","offer_id":47944464302310,"sku":"CLIBSSELZCO50","price":499.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CLIBSSELZCO_main.jpg?v=1783061056","url":"https:\/\/echemsupplies.com\/products\/clibsselzco","provider":"EChem Supplies","version":"1.0","type":"link"}