{"product_id":"clibsselzsp","title":"LZSP (Li3Zr3Si3PO12) Powder as Solid-State Electrolyte for Lithium-Ion Battery, 25-100 g\/bottle, CLIBSSELZSP","description":"\u003cp\u003eLZSP powder—cataloged under commercial trade labels as \"Li3Zr3Si3PO12\" but crystallographically defined as the solid-solution NASICON composition Li3Zr2Si2PO12 (x = 2 in the Li{1+x}Zr2SixP{3-x}O12 series)—is a lithium-ion conducting ceramic solid-state electrolyte. Its primary utility lies in providing a titanium-free, low-density NASICON framework that circumvents the rapid electrochemical reduction seen in traditional titanium-based NASICONs (such as LATP) while offering superior ambient air\/moisture stability compared to garnet-type oxides (LLZO).\u003c\/p\u003e\n\u003cp\u003eThe primary applications in battery systems are: (1) \u003cstrong\u003eActive Ceramic Filler in Composite Polymer Electrolytes (CPEs)\u003c\/strong\u003e: Sub-micron LZSP powder (D50=~ 0.3–0.8 um) is blended at loadings of 10–40 wt% into polymer matrices such as PEO, PVDF-HFP, or poly(acrylonitrile) (PAN). It disrupts polymer chain crystallinity to promote segmental motion, provides high-mobility Lewis acid-base interfacial pathways, and reinforces mechanical stiffness against soft dendrite deformation. (2) \u003cstrong\u003eTape-Cast Composite Separator Films\u003c\/strong\u003e: Slurry-cast onto release liners with polymeric binders (e.g., poly(acrylic acid) or PVDF) to form ultrathin (15–30 um), flexible solid-state separator sheets. (3) \u003cstrong\u003eInorganic Catholyte for Composite Cathodes\u003c\/strong\u003e: Milled dry with cathode active materials (CAMs like LFP or high-Ni NMC) and conductive carbon to create continuous 3D inorganic Li+ percolation channels inside high-loading positive electrodes.\u003c\/p\u003e\n\u003ctable width=\"100%\" style=\"width: 100%; height: 243.2px;\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 30.4922%; height: 35.6px;\"\u003e\u003cem\u003ePart Number\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.1869%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003eCLIBSSELZSP (C-LIB-SSE-LZSP)\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 30.4922%; height: 35.6px;\"\u003e\u003cem\u003eChemical Formula\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.1869%; height: 35.6px;\"\u003e\n\u003cp\u003eLi3Zr3Si3PO12\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 30.4922%; height: 35.6px;\"\u003e\u003cem\u003eAppearance\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.1869%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003eWhite Powder\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 30.4922%; height: 35.6px;\"\u003e\n\u003cstrong\u003e \u003c\/strong\u003e\u003cem\u003ePurity\u003c\/em\u003e\n\u003c\/td\u003e\n\u003ctd style=\"width: 69.1869%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003e\u0026gt;99.9% \u003c\/span\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003eLi2O: 8.23 wt%, La2O3: 9.63 wt%,  Na2O: 3.65 wt%\u003c\/span\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003eP2O5: 13.58 wt%,  ZrO2: 40.76 wt%,  SiO2: 24.05 wt%\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 30.4922%; height: 35.6px;\"\u003eDensity\u003c\/td\u003e\n\u003ctd style=\"width: 69.1869%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003e~3.0-3.5 g\/cm3\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 30.4922%; height: 35.6px;\"\u003e\u003cem\u003eSize Distribution\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.1869%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003eD50 ~ 300 nm\u003c\/span\u003e\u003cspan\u003e \u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 10px;\"\u003e\n\u003ctd style=\"width: 30.4922%; height: 10px;\"\u003e\u003cem\u003eIonic Conductivity\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.1869%; height: 10px;\"\u003e\n\u003cp\u003e\u003cspan\u003e~3.59 x10-3 S\/cm at 25 °C\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 19.6px;\"\u003e\n\u003ctd style=\"width: 30.4922%; height: 19.6px;\"\u003e\u003cem\u003ePackage Size\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.1869%; height: 19.6px;\"\u003e25 g, 50 g, and 100 g\/bottle\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e\u003cbr\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eNotes\u003c\/strong\u003e: Please try to store the LZSP powders in a dry place (glovebox is best).\u003c\/span\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eReferences\u003c\/strong\u003e: \u003c\/span\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\u003cspan\u003e\u003ca href=\"https:\/\/www.science.org\/doi\/full\/10.1126\/sciadv.abj7698\"\u003eL. Zhu, et al. Enhancing ionic conductivity in solid electrolyte by relocating diffusion ions to under-coordination sites, Science Advances, 2022, DOI: 10.1126\/sciadv.abj76\u003c\/a\u003e\u003c\/span\u003e\u003c\/li\u003e\n\u003cli\u003e\u003ca href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/smll.202402164\"\u003e\u003cspan\u003eN. Zhang, et al. Slurry Casted Ultrathin Li3Zr2Si2PO12 Electrolyte Film for Solid-State Lithium Metal Batteries, Small, 2024, 20, 2402164\u003c\/span\u003e\u003c\/a\u003e\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"EChem Supplies","offers":[{"title":"25 g","offer_id":48311543202022,"sku":"CLIBSSELZSP25","price":99.0,"currency_code":"USD","in_stock":true},{"title":"50 g","offer_id":48311543234790,"sku":"CLIBSSELZSP50","price":179.0,"currency_code":"USD","in_stock":true},{"title":"100 g","offer_id":48311543267558,"sku":"CLIBSSELZSP100","price":319.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CLIBSSELZSP_main.jpg?v=1789031079","url":"https:\/\/echemsupplies.com\/products\/clibsselzsp","provider":"EChem Supplies","version":"1.0","type":"link"}