{"product_id":"csibesnco","title":"NaClO4 Powder (\u003e99.99%) as Electrolyte Salt for Sodium-Ion Battery, 50-200g\/bottle, CSIBESNCO","description":"\u003cp\u003eSodium perchlorate (NaClO4) powder (battery\/electrochemical grade) is the standard reference and model electrolyte salt in academic and early-stage sodium-ion battery (SIB) research. Its primary utility comes from being fluorine-free and hydrolysis-inert: unlike NaPF6, it cannot generate hydrofluoric acid (HF) when exposed to trace water, making it a reliable baseline for studying moisture-sensitive cathodes (Prussian Blue\/White, layered oxides) and fundamental interphase phenomena.\u003c\/p\u003e\n\u003cp\u003eKey physicochemical features for the NaClO4 as SIB electrolyte salt are: (1)\u003cstrong\u003e Zero HF Generation \u0026amp; Hydrolysis Immunity\u003c\/strong\u003e: NaPF6 reacts spontaneously with sub-ppm moisture or crystal water to generate toxic, corrosive HF and POF3. NaClO4 is hydrolytically inert. It does not generate acidic decomposition products in the presence of water, making it the preferred salt for: (i) \u003cem\u003ePrussian Blue \u0026amp; Prussian White (PBA\/PWA)\u003c\/em\u003e: Eliminates acid-catalyzed Fe\/Mn transition metal leaching from the open cyanide framework. (ii) \u003cem\u003eBasic Layered Oxides (NFM, NNMO)\u003c\/em\u003e: Prevents chemical etching of particle surfaces by acidic species. (2) \u003cstrong\u003eBroad Anodic Stability (\u0026gt;4.5 V vs. Na\/Na+)\u003c\/strong\u003e: The tetrahedral perchlorate anion exhibits high oxidative resistance in cyclic carbonates like propylene carbonate (PC) and ethylene carbonate (EC), allowing unhindered evaluation of high-voltage cathodes like P2-Na2\/3Ni1\/3Mn2\/3O2 (4.2 V) and Na3V2(PO4)2F3 (4.3 V). (3) \u003cstrong\u003eLow Formula Weight Gravimetric Benefit\u003c\/strong\u003e: At 122.44 g\/mol, it requires roughly 27% less mass than NaPF6 (167.95 g\/mol) and 40% less than NaFSI (203.11 g\/mol) to achieve a target molarity and reducing inactive electrolyte dead weight. \u003c\/p\u003e\n\u003ctable style=\"width: 100%; height: 310.725px;\" width=\"100%\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 35.6px;\"\u003e\u003cem\u003ePart Number\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003eCSIBESNCO (C-SIB-ES-NCO)\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 38.325px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 38.325px;\"\u003e\u003cem\u003eChemical Formula\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 38.325px;\"\u003e\n\u003cp\u003eNaClO4\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 35.6px;\"\u003e\u003cem\u003eCAS\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003e7601-89-0\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 35.6px;\"\u003e\u003cem\u003eAppearance\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003eWhite Powder\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 106.8px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 106.8px;\"\u003e\n\u003cstrong\u003e \u003c\/strong\u003e\u003cem\u003ePurity\u003c\/em\u003e\n\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 106.8px;\"\u003e\n\u003cp\u003e\u003cspan\u003e\u0026gt;99.99% (Battery Grade)\u003c\/span\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003eHumidity level: \u0026lt;50 ppm \u003c\/span\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003echloride (Cl-): ≤30 ppm, sulfate (SO42-): ≤20 ppm\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 19.6px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 19.6px;\"\u003e\u003cem\u003eMolecular Weight\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 19.6px;\"\u003e\u003cspan\u003e122.44 g\/mol\u003c\/span\u003e\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 19.6px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 19.6px;\"\u003e\u003cem\u003eMelt Point\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 19.6px;\"\u003e\u003cspan\u003e482 °C\u003c\/span\u003e\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 19.6px;\"\u003e\n\u003ctd style=\"width: 33.6331%; height: 19.6px;\"\u003e\u003cem\u003ePackage Size\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 66.0072%; height: 19.6px;\"\u003e\u003cspan\u003e50 g, 100 g, and 200 g\/bottle\u003c\/span\u003e\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e\u003cbr\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eNotes\u003c\/strong\u003e: Please store the NaClO4 powder in a dry place (glovebox is the best option)\u003c\/span\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eReferences\u003c\/strong\u003e: \u003c\/span\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\u003cspan\u003e\u003ca href=\"https:\/\/pubs.acs.org\/ancac3\/article-abstract\/17\/18\/18608\/314549\/Electrolyte-Salts-for-Sodium-Ion-Batteries-NaPF6?redirectedFrom=fulltext\"\u003eF. Cheng, et al. Electrolyte Salts for Sodium-Ion Batteries: NaPF6 or NaClO4?, ACS Nano (2023) 17 (18): 18608–18615.\u003c\/a\u003e\u003c\/span\u003e\u003c\/li\u003e\n\u003cli\u003e\u003cspan\u003e\u003ca href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S0378775322011521\"\u003eY. X. Li, et al. NaClO4 as an effective electrolyte additive for high-energy Li-ion batteries, Journal of Power Sources, 2022, 551, 232175\u003c\/a\u003e \u003c\/span\u003e\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"DDDC","offers":[{"title":"50 g","offer_id":48331164877030,"sku":"CSIBESNCO50","price":119.0,"currency_code":"USD","in_stock":true},{"title":"100 g","offer_id":48331164909798,"sku":"CSIBESNCO100","price":209.0,"currency_code":"USD","in_stock":true},{"title":"200 g","offer_id":48331164942566,"sku":"CSIBESNCO200","price":379.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CSIBESNCO_main.jpg?v=1789151174","url":"https:\/\/echemsupplies.com\/products\/csibesnco","provider":"EChem Supplies","version":"1.0","type":"link"}