{"product_id":"csibpcnfm111oh","title":"Ni1\/3Fe1\/3Mn1\/3(OH)2 Precursor Powder for O3-Type Layered Oxide NaNi1\/3Fe1\/3Mn1\/3O2 Cathode Synthesis, 100 g\/bottle, CSIBPCNFM111OH","description":"\u003cp\u003eThe Ni1\/3Fe1\/3Mn1\/3(OH)2 precursor powder (often designated as an NFM hydroxide precursor) is a critical raw material primarily utilized for the synthesis of transition metal layered oxide cathode materials (NaNi1\/3Fe1\/3Mn1\/3O2) in sodium-ion batteries (SIBs). By replacing expensive and supply-constrained cobalt (Co) with abundant, low-cost iron (Fe), this ternary precursor system serves as the structural backbone for high-capacity O3-type or P2-type sodium layered oxides.\u003c\/p\u003e\n\u003cdiv style=\"text-align: left;\"\u003eA high-quality Ni1\/3Fe1\/3Mn1\/3(OH)2 precursor typically targets specific morphological and structural characteristics to ensure smooth solid-state calcination with sodium salts (e.g., Na2CO3): (1) \u003cstrong\u003eMorphology\u003c\/strong\u003e: Highly spherical, dense secondary particles composed of tightly packed, plate-like or needle-like primary crystals. (2) \u003cstrong\u003eParticle Size Distribution\u003c\/strong\u003e: Typically controlled within a narrow range, such as a D50 around 4–8 um (resulting in a final lithiated\/sodiated cathode D50 of roughly 7–10 um). (3) \u003cstrong\u003eTap Density\u003c\/strong\u003e: Generally targeted above 1.2–1.5 g\/cm³ to ensure the final cathode exhibits the high volumetric energy density required for commercial cells. (4) \u003cstrong\u003eCrystal Structure\u003c\/strong\u003e: It crystallizes in a β-Ni(OH)2-type hexagonal structure, where Fe^{2+\/3+} and Mn^{2+} successfully substitute into the nickel hydroxide host lattice.\u003c\/div\u003e\n\u003cdiv style=\"text-align: left;\"\u003e\u003cbr\u003e\u003c\/div\u003e\n\u003cdiv style=\"text-align: left;\"\u003e\n\u003cp data-path-to-node=\"14\"\u003eTo transition from the precursor powder to the active cathode material (\u003cspan class=\"math-inline\" data-math=\"\\text{NaNi}_{1\/3}\\text{Fe}_{1\/3}\\text{Mn}_{1\/3}\\text{O}_2\" data-index-in-node=\"72\"\u003eNaNi1\/3Fe1\/3Mn1\/3O2\u003c\/span\u003e), the powder undergoes high-temperature calcination:\u003c\/p\u003e\n\u003cp data-path-to-node=\"14\"\u003e\u003cimg src=\"https:\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CSIBPCNFMOH_04.png?v=1779676782\" alt=\"\" width=\"530\" height=\"68\"\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cstrong\u003eSintering Conditions\u003c\/strong\u003e: The precursor is intimately blended with a sodium source and fired in a roller hearth kiln or tube furnace at temperatures ranging from 750°C to 900°C under air or oxygen.\u003c\/p\u003e\n\u003cp\u003e\u003cstrong\u003eStructural Outcome\u003c\/strong\u003e: Depending on the exact sintering temperature and cooling profile, it forms an O3-type or P2-type layered structure. The O3 phase offers higher initial discharge capacities (typically around 120–135 mAh\/g), while the P2 phase generally delivers superior rate capability.\u003c\/p\u003e\n\u003c\/div\u003e\n\u003ctable width=\"100%\" style=\"width: 100%; height: 269.325px;\"\u003e\n\u003ctbody\u003e\n\u003ctr style=\"height: 46.8875px;\"\u003e\n\u003ctd style=\"width: 30.5755%; height: 46.8875px;\"\u003e\u003cem\u003ePart Number\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.0647%; height: 46.8875px;\"\u003e\n\u003cp\u003e\u003cspan\u003eCSIBPCNFM111OH (C-SIB-PC-NFM111OH)\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 13.8875px;\"\u003e\n\u003ctd style=\"width: 30.5755%; height: 13.8875px;\"\u003e\u003cem\u003ePurity\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.0647%; height: 13.8875px;\"\u003e\n\u003cp\u003e\u003cspan\u003e\u0026gt;99.9% (Ni:Fe:Mn=33.5: 33.25: 33.25)\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 71.2px;\"\u003e\n\u003ctd style=\"width: 30.5755%; height: 71.2px;\"\u003e\u003cem\u003eImpurity\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.0647%; height: 71.2px;\"\u003e\n\u003cp\u003e\u003cspan\u003eNa\u0026lt;71 ppm,   Mg\u0026lt;55 ppm,   Si\u0026lt;45 ppm\u003c\/span\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003eCr\u0026lt;30 ppm,  Cu\u0026lt;3 ppm,  S\u0026lt;191 ppm\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 46.8875px;\"\u003e\n\u003ctd style=\"width: 30.5755%; height: 46.8875px;\"\u003e\n\u003cstrong\u003e \u003c\/strong\u003e\u003cem\u003eParticle Size Distribution\u003c\/em\u003e\n\u003c\/td\u003e\n\u003ctd style=\"width: 69.0647%; height: 46.8875px;\"\u003e\n\u003cp\u003e\u003cspan\u003eD10: 6.3 um;  D50 =8.3 um;  D90 = 10.8 um;  D95: 11.5 um\u003c\/span\u003e\u003cspan\u003e\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 35.6px;\"\u003e\n\u003ctd style=\"width: 30.5755%; height: 35.6px;\"\u003eWater Level\u003c\/td\u003e\n\u003ctd style=\"width: 69.0647%; height: 35.6px;\"\u003e\n\u003cp\u003e\u003cspan\u003e\u0026lt;530 ppm\u003c\/span\u003e\u003c\/p\u003e\n\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 28.5625px;\"\u003e\n\u003ctd style=\"width: 30.5755%; height: 28.5625px;\"\u003e\u003cem\u003eTap Density\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.0647%; height: 28.5625px;\"\u003e1.84 g\/cm3\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003ctr style=\"height: 26.3px;\"\u003e\n\u003ctd style=\"width: 30.5755%; height: 26.3px;\"\u003e\u003cem\u003eSpecific Area (BET)\u003c\/em\u003e\u003c\/td\u003e\n\u003ctd style=\"width: 69.0647%; height: 26.3px;\"\u003e15.56 m2\/g\u003c\/td\u003e\n\u003c\/tr\u003e\n\u003c\/tbody\u003e\n\u003c\/table\u003e\n\u003cp\u003e \u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eNotes\u003c\/strong\u003e: (1) Please store the Ni1\/3Fe1\/3Mn1\/3(OH)2 precursor powder in a dry area (glovebox is preferred); \u003c\/span\u003e\u003cspan\u003e(2) The battery precursor powder is highly recommended to be dried at 80-100°C in a vacuum oven for 6-12 h before use. \u003c\/span\u003e\u003c\/p\u003e\n\u003cp\u003e\u003cspan\u003e\u003cstrong\u003eReferences\u003c\/strong\u003e: \u003c\/span\u003e\u003c\/p\u003e\n\u003col\u003e\n\u003cli\u003e\u003cspan\u003e\u003ca href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S0009250925014216\"\u003eP. Luo, et al. Physics-informed machine learning framework for predictive control of particle size distribution in Ni1\/3Fe1\/3Mn1\/3(OH)2 synthesis, Chemical Engineering Science, 2026, 320, 122600\u003c\/a\u003e\u003c\/span\u003e\u003c\/li\u003e\n\u003cli\u003e\u003cspan\u003e\u003ca href=\"https:\/\/iopscience.iop.org\/article\/10.1149\/1945-7111\/ace55a\/meta\"\u003eL. Zhang, et al. Impact of Calcium on Air Stability of Na[Ni1\/3Fe1\/3Mn1\/3]O2 Positive Electrode Material for Sodium-ion Batteries, J. Electrochem. Soc., 2023, 170 070514\u003c\/a\u003e \u003c\/span\u003e\u003c\/li\u003e\n\u003c\/ol\u003e","brand":"JFXNY","offers":[{"title":"Default Title","offer_id":47709909680358,"sku":"CSIBPCNFM111OH","price":89.0,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0774\/6591\/1526\/files\/CSIBPCNFM111OH_main.png?v=1779686244","url":"https:\/\/echemsupplies.com\/products\/csibpcnfm111oh","provider":"EChem Supplies","version":"1.0","type":"link"}