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NiO (73 wt%) Electrode Slurry for SOFC/SOEC, 100 g/bottle, CSOFECESNiO

NiO (73 wt%) Electrode Slurry for SOFC/SOEC, 100 g/bottle, CSOFECESNiO

$149.00 USD
In Stock SKU: CSOFECESNiO
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In the fabrication of Solid Oxide Fuel Cells (SOFC) and Electrolysis Cells (SOEC), a NiO (Nickel Oxide) slurry is the liquid suspension used to deposit the precursor for the hydrogen electrode. While most industrial applications use a composite NiO/YSZ or NiO/GDC slurry, pure NiO slurries are often used in research for infiltration techniques or as a contact layer to improve current collection. The primary function of the NiO slurry is to provide a high-surface-area coating that, upon reduction to metallic Nickel (Ni), becomes the catalyst for hydrogen oxidation or water splitting.

The multi-components of NiO slurry are:

Functional Roles of NiO in the Slurry: (1) Catalytic Precursor: NiO is a ceramic insulator. It must be reduced in situ using hydrogen gas (NiO + H2 → Ni + H2O) to become the active catalyst. (2) Porosity Generation: Metallic Ni has a molar volume ~40% smaller than NiO. This volume contraction during the first run of the cell creates the micro-porosity necessary for gas molecules to reach the reaction sites. (3) Electronic Connectivity: Once reduced, the Ni particles must touch each other to form a "percolation network" that carries electrons from the reaction site to the external circuit.

Part Number

CSOFECESNiO (C-SOFEC-ES-NiO)

Active Material

NiO

Solid state content: 73 wt%

Package Grade

100 g/bottle (other grades, such as 500 g, and 1000 g or larger can be supplied upon request)

References:

  1. M. B. Mogensen, et al., Ni migration in solid oxide cell electrodes: Review and revised hypothesis, Fuel Cells, 2021, 21, 415-429
  2. A. Hauch, et al., Ni/YSZ electrodes structures optimized for increased electrolysis performance and durability, Solid State Ionics, 2016, 293, 27-36

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