PP13PF6 (1-Methyl-1-Propylpiperidinium hexafluorophosphate, >99.9%) Ionic Liquid as Battery Electrolyte Solvent, 25-100 g/bottle, CBESPP13PF6
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PP13PF6 (1-Methyl-1-propylpiperidinium hexafluorophosphate) is an ionic liquid that combines an aliphatic, 6-membered piperidinium cation with the phosphorus-based hexafluorophosphate (PF6^-) anion. By pairing the highly reduction-resistant piperidinium ring with a PF6^- anion, this formulation attempts to merge the robust cathodic stability of saturated cyclic ammonium cations with the structural familiarity of PF6^- salts commonly used in conventional lithium-ion batteries. However, its deployment as a battery electrolyte solvent brings specific chemical trade-offs.
The key physicochemical characteristics of PP13PF6 are: (1) High Cathodic Stability: Unlike aromatic cations (such as imidazolium in EMIMPF6), the saturated 6-membered piperidinium ring (PP13) exhibits excellent resistance against reduction. This makes it significantly more compatible with carbonaceous anodes or high-voltage reductive environments. (2) Thermal Safety & Non-Volatility: Like other ionic liquids, PP13PF6 is non-flammable, has negligible vapor pressure, and maintains high thermal stability, effectively eliminating the volatile fire risks tied to organic carbonate blends.
| Part Number |
CBESPP13PF6 (C-BES-PP13PF6) |
| CAS |
1426821-81-9 |
| Chemical Formula |
C₉H₂₀F₆NP ![]() |
| Appearance | White to yellowish / off-white |
| Purity |
>99.9% (Battery Grade) |
| Molecular Weight | 287.23 g/mol |
| Density | 1.283 g/cm3 |
| Package Size | 25 g, 50 g, and 100 g/bottle |
Notes: Please try to store the PP13PF6 in a dry place (dryroom or glovebox is preferred).
References:
- M. Mirarabrazi, et al. Solid–Liquid Equilibria for Hexafluorophosphate-Based Ionic Liquid Quaternary Mixtures and Their Corresponding Subsystems, J. Phys. Chem. B (2019) 123 (42): 8954–8969.
- R. A. Di Leo, et al. Battery electrolytes based on saturated ring ionic liquids: Physical and electrochemical properties, Electrochimica Acta, 2013, 109, 27-32
