Py12TFSI {1-Ethyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, >99.9%} Ionic Liquid as Battery Electrolyte Solvent, 25-100 g/bottle, CBESPy12TFSI
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Py12TFSI (1-Ethyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide) is a prominent room-temperature ionic liquid (RTIL) engineered for advanced electrochemical devices, including lithium-metal batteries, high-voltage sodium-ion systems, and supercapacitors. Composed of an aliphatic quaternary ammonium pyrrolidinium cation and a heavily fluorinated imide anion, it offers a distinct profile of stability compared to conventional organic carbonate solvents.
The key physicochemical & electrochemical characteristics are: (1) Wide Electrochemical Window: Py12TFSI features a broad stability window (typically exceeding 5.0-6.0 V vs. Li/Li+), making it structurally resilient against high-potential cathode surfaces—such as high-voltage olivines (like LMFP) or high-nickel layered oxides. (2) Thermal Safety & Non-Volatility: Like other members of the pyrrolidinium family, it is non-volatile, non-flammable, and exhibits high thermal decomposition thresholds, drastically reducing risks associated with thermal runaway. (3) Anodic vs. Cathodic Stability: The aliphatic pyrrolidinium ring provides superior resistance against reduction at negative potentials compared to aromatic cations (like imidazolium), lending itself well to stable cycling with carbonaceous anodes or lithium metal.
| Part Number |
CBESPy12TFSI (C-BES-Py12TFSI) |
| CAS |
223436-99-5 |
| Chemical Formula |
C₉H₁₆F₆N₂O₄S₂ ![]() |
| Appearance |
Solid/powder to crystal |
| Purity |
>99.9% (Battery Grade) Humidity level<100 ppm |
| Molecular Weight | 394.35 g/mol |
| Density | ~1.183 g/cm3 |
| Package Size | 25 g, 50 g, and 100 g/bottle |
Notes: Please try to store the Py12TFSI in a dry place (dryroom or glovebox is preferred option).
References:
- M. Jabeen, et al. Thermally Adaptive PVDF-HFP/Ionic Liquid Electrolyte Enabling Stable SEI/CEI Formation in Sodium Metal Batteries, Adv. Funct. Mater., 2026, 36, e25343
- S. A. Langevin, et al. Enabling wide temperature battery operation with hybrid lithium electrolytes, Chem. Commun. (2024) 60 (40): 5298–5301.
