TMSB (Tris(trimethylsilyl) Borate, 99.9%) as Battery Electrolyte Additive, 25 g/bottle, CBEATMSB
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TMSB additives perform a dual-functional role in the battery cell by acting as both an acid scavenger and an interphase-forming agent. TMSB additives help form stable protective layers on both electrodes.
(1) Cathode Electrolyte Interphase (CEI): TMSB is often preferentially oxidized at the high potential of the cathode surface (especially >4.3 V), forming a thin, stable Si- and B-rich protective film. This CEI acts as a barrier, suppressing the oxidative decomposition of the main carbonate solvents and reducing impedance buildup, which is crucial for high voltage cycling stability.
(2) Solid Electrolyte Interphase (SEI): Research shows that TMSB can also contribute to forming a more stable and less resistive SEI on the graphite anode, particularly at elevated temperatures. This stabilizes the anode and reduces resistance to lithium-ion transport.
| Part Number |
CBEATMSB (C-BEA-TMSB) |
| CAS |
4325-85-3 |
| Chemical Formula |
[(CH3)3SiO]3B ![]() |
| Appearance |
Colorless Liquid |
| Purity |
99.0% (Battery Grade) |
| Molecular Weight | 278.38 g/mol |
| Boiling Point | ~186 °C/720 mmHg (lit.) |
| Density | 0.831 g/mL at 25 °C (lit.) |
| Package Size | 25 g/bottle |
Notes: Please store the TMSB solution in the glovebox due to its sensitivity to humidity and oxygen
References:
- Z. Cai, et al. Tris(trimethylsilyl) borate as electrolyte additive to improve performance of lithium-ion batteries, J. Power Sources, 2012, 202, 341-346.
- K. Wang, et al. A comparative study of Si-containing electrolyte additives for lithium ion battery: Which one is better and why is it better, J. Power Sources, 2017, 342, 677-684.
