Skip to product information
HAZMAT
TMSB (Tris(trimethylsilyl) Borate, 99.9%) as Battery Electrolyte Additive, 25 g/bottle, CBEATMSB

TMSB (Tris(trimethylsilyl) Borate, 99.9%) as Battery Electrolyte Additive, 25 g/bottle, CBEATMSB

$79.00 USD
Backorder SKU: CBEATMSB
Use your own shipping account?

We support FedEx, UPS, and DHL third-party billing for institutional customers.

Place your order first, then email shipping@echemsupplies.com with your account details and order number. We'll generate the label using your account and refund your shipping charges, less a handling fee.

Review third-party shipping terms →


TMSB additives perform a dual-functional role in the battery cell by acting as both an acid scavenger and an interphase-forming agent. TMSB additives help form stable protective layers on both electrodes.

(1) Cathode Electrolyte Interphase (CEI): TMSB is often preferentially oxidized at the high potential of the cathode surface (especially >4.3 V), forming a thin, stable Si- and B-rich protective film. This CEI acts as a barrier, suppressing the oxidative decomposition of the main carbonate solvents and reducing impedance buildup, which is crucial for high voltage cycling stability. 

(2) Solid Electrolyte Interphase (SEI): Research shows that TMSB can also contribute to forming a more stable and less resistive SEI on the graphite anode, particularly at elevated temperatures. This stabilizes the anode and reduces resistance to lithium-ion transport.

Part Number

CBEATMSB (C-BEA-TMSB)

CAS

4325-85-3

Chemical Formula

[(CH3)3SiO]3B

Appearance

Colorless Liquid

 Purity

99.0% (Battery Grade)

Molecular Weight 278.38 g/mol
Boiling Point ~186 °C/720 mmHg (lit.)
Density 0.831 g/mL at 25 °C (lit.)
Package Size 25 g/bottle

 

Notes: Please store the TMSB solution in the glovebox due to its sensitivity to humidity and oxygen 

References

  1. Z. Cai, et al. Tris(trimethylsilyl) borate as electrolyte additive to improve performance of lithium-ion batteries, J. Power Sources, 2012, 202, 341-346.
  2. K. Wang, et al. A comparative study of Si-containing electrolyte additives for lithium ion battery: Which one is better and why is it better, J. Power Sources, 2017, 342, 677-684

You may also like