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MIL-53(Al) Metal Organic Frameworks (MOFs) Powder for Gas Absorption and Separation, CGASMOFMIL53Al

MIL-53(Al) Metal Organic Frameworks (MOFs) Powder for Gas Absorption and Separation, CGASMOFMIL53Al

$199.00 USD
In Stock SKU: CGASMOFMIL53AlW5
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MIL-53(Al) (Materials of Institut Lavoisier-53, aluminum terephthalate, Al(OH)[O2C–C6H4–CO2) is one of the most widely studied flexible Metal-Organic Frameworks (MOFs). Constructed from corner-sharing AlO4(OH)2 octahedral chains cross-linked by 1,4-benzenedicarboxylate (BDC) linkers, it forms 1D rhombic diamond-shaped pore channels known for their reversible structural transitions.

The critical features of the MIL-53(Al) are shown below: (1) Reversible "Breathing Effect": MIL-53(Al) transitions between a Large Pore (LP) form (open diamond channel, pore diameter ~ 8.5–12Å, unit cell volume ~ 1480Å^3) and a Narrow Pore (NP) form (contracted channel, pore diameter ~ 2.6–3.5Å, unit cell volume ~ 1000Å^3). This transition is triggered by guest molecule adsorption, temperature, or external mechanical pressure. (2) High Hydrothermal & Thermal Stability: Unlike many zinc- or copper-based MOFs (such as MOF-5 or HKUST-1), MIL-53(Al) resists moisture degradation and remains thermally stable up to ~ 450–500°C in air/inert environments. (3) Textural Properties: BET Surface Area: Typically 1100–1600 m2/g (depending on activation and synthesis route).

Part Number CGASMOFMIL53Al (C-GAS-MOF-MIL53Al)
CAS 654061-20-8
Color White Powder
Size 50-200 nm
BET >1000 m2/g
Pore Size 0.4-0.8 nm
Primary Applications

Gas absorption, storage, and separation. 

Wastewater treatment, ion separation, 

Package Grade 5 g, 10 g, and 20 g/bottle


References:

  1. F. Zhang, et al., Hydrogen Selective NH2-MIL-53(Al) MOF Membranes with High Permeability, Adv. Funct. Mater., 2012, 22, 3583-3590.
  2. P. Mishra, et al., Adsorption and Separation of Carbon Dioxide Using MIL-53(Al) Metal-Organic Framework, Ind. Eng. Chem. Res. (2014) 53 (51): 19747–19753.

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