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LiPF6/PVDF-HFP-Based Gel Polymer Electrolyte for Li-Ion Battery, 50-200 g/bottle, CGPELPFPVDFHFP

LiPF6/PVDF-HFP-Based Gel Polymer Electrolyte for Li-Ion Battery, 50-200 g/bottle, CGPELPFPVDFHFP

$129.00 USD
In Stock SKU: CGPELPFPVDFHFP50
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Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP)-based Gel Polymer Electrolyte (GPE) plasticized with a LiPF6-carbonate liquid electrolyte represents one of the most mechanically robust and electrochemically stable gel systems for advanced lithium-ion batteries

The main features of the LiPF6/PVDF-HFP-Based gel polymer electrolyte are: (1) Dual-Phase Morphology: The semi-crystalline structure features crystalline PVDF blocks providing structural integrity and mechanical strength, while amorphous HFP domains swell extensively with liquid carbonate electrolytes, trapping them within a three-dimensional polymer network. (2) High Ionic Conductivity: Swelling with 1.0 M LiPF6 liquid electrolyte yields high room-temperature ionic conductivity (>10^{-3} S/cm comparable to liquid electrolytes while eliminating free-flowing liquid leakage risks. (3) Interfacial Compatibility: Exhibits excellent wettability and stable solid electrolyte interphase (SEI) formation when paired with both high-voltage cathodes and graphite or silicon-carbon anodes.

Part Number

CGPELPFPVDFHFP (C-GPE-LPFPVDFHFP)

Appearance

Transparent gel

Gel Composition

1.0 M LiPF6 in EC:DMC=1:1 vol% + 5% FEC

Host polymer matrix: 20 wt% PVDF-HFP

Plasticizer: 5 wt% Dibutyl phthalate (DBP)

Solvent: Anhydrous acetone

Viscosity

~1000-1500 mPa*s

Solid Content

~20%

Ionic Conductivity

~1.0-4.4 x10-3 S/cm at RT

Electrochemical Window

4.5-4.8 V

Package Size 50 g, 100 g, and 200 g/bottle


Notes: Please try to store the LiPF6/PVDF-HFP gel polymer electrolyte in a dry place. 

References: 

  1. H. X. Yang, et al. Multiscale Structural Gel Polymer Electrolytes with Fast Li+ Transport for Long-Life Li Metal Batteries, Adv. Funct. Mater., 2023, 33, 2209837
  2. G. Chen, et al. A Flexible Dual-Ion Battery Based on PVDF-HFP-Modified Gel Polymer Electrolyte with Excellent Cycling Performance and Superior Rate Capability, Adv. Energy Mater., 2018, 8, 1801219. 

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