Silicon Nitride (Si3N4) Milling Balls (2-20 mm), 10-200 pcs/bag, MBSi3N4
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Silicon Nitride (Si3N4) Milling Balls represent an elite, ultra-robust class of non-oxide ceramic grinding media. Sintered under extreme conditions via Hot Isostatic Pressing (HIP) or gas-pressure sintering, silicon nitride features a distinct needle-like, interlocking D50 microstructure that gives it a unique balance of extreme hardness, electrical insulation, and lightweight kinetics. While YSZ (Zirconia) and Tungsten Carbide dominate standard laboratory tasks, silicon nitride is specified for applications that demand high-speed processing, absolute non-oxide chemical purity, or zero magnetic/electrical interference.
The key advantages of the Si3N4 milling balls are: (1) Ultra-Low Wear and Contamination Rates: Comparative mechanical wear tests show that silicon nitride can sustain up to 14% less weight loss than alternative oxide ceramics under identical high-energy impacting conditions. The exceptional grain-boundary toughness prevents fine sample particles from anchoring into and fracturing the media surface. Any microscopic wear that does occur introduces only silicon (Si) and nitrogen (N)—both of which are easily tolerated or burned off in many advanced ceramic composites. (2) High-Speed Acceleration Kinetics: Because the density of Si3N4 is low (3.2 g/cm3), the media experiences much lower centrifugal forces at rest. In high-speed planetary or mixer mills this low mass dramatically reduces skidding and sliding along the inner walls during initial acceleration phases, converting the mill's energy into clean, direct impacts and high-efficiency attrition. (3) Absolute Non-Oxide and Semiconductor Purity: When processing materials for the semiconductor, photovoltaic, or structural non-oxide ceramic fields, utilizing oxide media like Alumina (Al2O3) or Zirconia (ZrO2) can introduce unwanted oxygen lattice defects into the matrix. Silicon nitride ensures a completely non-oxide processing path.
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