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NPGDA (Neopentyl glycol diacrylate, >95%} as Crosslinking Monomer for Gel Polymer Electrolyte, 50-200 g/bottle, CGPECMNPGDA

NPGDA (Neopentyl glycol diacrylate, >95%} as Crosslinking Monomer for Gel Polymer Electrolyte, 50-200 g/bottle, CGPECMNPGDA

$69.00 USD
In Stock SKU: CGPECMNPGDA50
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Neopentyl glycol diacrylate (NPGDA) is a bifunctional aliphatic acrylate monomer (C8H12O4) featuring two reactive acrylate (CH2=CHCOO-) groups attached to a hindered, symmetrical neopentyl glycol core (-CH2-C(CH}3)2-CH2-). In advanced energy storage research, NPGDA is utilized as a high-reactivity, rigid-core crosslinking agent for Gel Polymer Electrolytes (GPEs) and in situ polymerized solid/gel battery systems, delivering rapid curing kinetics, high chemical resistance, and robust mechanical rigidity for high-energy lithium and sodium metal batteries.

The main functional roles of NPGDA in GPEs are: (1) Rigid 3D Network & Liquid Immobilization: Upon thermal or UV-initiated radical polymerization (using initiators like AIBN, BPO, or photoinitiators), NPGDA crosslinks into a tightly knit 3D network that permanently traps and immobilizes organic liquid electrolytes. This eliminates free-flowing liquid leakage, converting high-energy liquid cells into safe, dimensionally stable gel systems. (2) Enhanced Mechanical Modulus & Suppressed Dendrite Penetration: Due to the sterically hindered, compact neopentyl core, NPGDA-based networks exhibit a higher shear modulus and mechanical rigidity than flexible polyether-based diacrylates. This creates a stiffer physical barrier that effectively resists sharp lithium or sodium dendrite propagation during fast-charging cycles. (3) High Thermal & Electrochemical Stability: The robust aliphatic ester backbone resists oxidative degradation at elevated voltages, helping maintain structural integrity when paired with high-voltage cathodes or operated at elevated temperatures.

Part Number

CGPECMNPGDA (C-GPE-CM-NPGDA)

CAS

2223-82-7

Chemical Formula

C11H16O4

Appearance

Colorless and clear liquid

Purity

>95% (stabilized by 200 ppm MEHQ)

Molecular Weight

212.24 g/mol

Density

1.031 g/mL at 25 °C (lit.)

Package Size 50 g, 100, and 200 g/bottle


Notes: Please try to store the NPGDA monomer in a dry and dark place.  

References: 

  1. Y. Liang, et al. Constructing a High-Performance Semi-interpenetrating Gel Polymer Electrolyte via In Situ Polymerization for Lithium Metal Batteries, ACS Appl. Polym. Mater. (2023) 5 (5): 3564–3573.
  2. Z. Wei, et al. In Situ-Polymerized Separator-Free Ionogel Electrolyte with Enhanced Interfacial Compatibility for Integrated Solid-State Lithium Batteries, Energy Fuels (2024) 38 (9): 8296–8305.

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