EOEOEA {2-(2-Ethoxyethoxy)ethyl acrylate, >99.0%} as Crosslinking Monomer for Gel Polymer Electrolytes (GPEs), 50-200 g/bottle, CGPECMEOEOEA
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EOEOEA (2-(2-Ethoxyethoxy)ethyl acrylate) (C9H16O4) is a flexible, long-chain monofunctional acrylate monomer featuring an ethoxyethoxyethyl oligo(ethylene glycol) ether side chain attached to a reactive acrylate group. While multifunctional crosslinkers provide primary 3D network connectivity, EOEOEA is utilized in advanced energy storage research as a specialized, highly flexible functional co-monomer and reactive diluent for Gel Polymer Electrolytes (GPEs) and solid-state polymer electrolyte systems. It combines low liquid viscosity with PEO-like ether oxygen linkages that actively assist in alkali metal ion solvation and local chain segmental motion.
Its main structural features are: (1) Oligo-Ether Side Chain Architecture: Features a recurring ether-oxygen sequence (-CH2CH2OCH2CH2OCH2CH3) that structurally mimics short segments of polyethylene oxide (PEO). This local chemical environment promotes Lewis acid-base coordination with lithium (Li+) or sodium (Na+) ions. (2) Low Liquid Viscosity & Reactive Dilution: Possesses very low room-temperature viscosity and high boiling characteristics, functioning as an efficient reactive diluent that dissolves readily in aprotic carbonate binary/ternary solvent blends (EC/DEC/DMC/PC) and thoroughly wets porous separator membranes (glass fiber, PE/PP) and dense electrode microstructures prior to curing. (3) Exceptional Chain Flexibility & Low Tg: The flexible ethoxyethoxyethyl tail imparts a very low glass transition temperature (Tg) to the resulting polymer chains, enhancing amorphous domain mobility and preventing embrittlement during prolonged charge-discharge cycling. (4) Rapid Acrylate Polymerization Kinetics: As an acrylate derivative, EOEOEA exhibits fast free-radical propagation rates under thermal or UV activation, ensuring efficient copolymerization into the growing 3D polymer network.
| Part Number |
CGPECMEOEOEA (C-GPE-CM-EOEOEA) |
| CAS |
7328-17-8 |
| Chemical Formula |
C₉H₁₆O₄ ![]() |
| Molecular Weight |
188.22 g/mol |
| Appearance |
Colorless liquid |
| Purity |
>99.0% |
| Density |
1.03 g/mL |
| Viscosity |
3-10 cps |
| Package Size | 50 g, 100 g, and 200 g/bottle |
Notes: Please try to store the EOEOEA liquid in a dry place and dark place.
References:
- C. Liu, et al. In Situ Construction of Zwitterionic Polymer Electrolytes with Synergistic Cation–Anion Regulation Functions for Lithium Metal Batteries, Adv. Funct. Mater., 2024, 34, 2307248
- Z. Qiu, et al. Surface activated polyethylene separator promoting Li+ ion transport in gel polymer electrolytes and cycling stability of Li-metal anode, Chemical Engineering Journal, 2019, 368, 321-330
