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EOEOEA {2-(2-Ethoxyethoxy)ethyl acrylate, >99.0%} as Crosslinking Monomer for Gel Polymer Electrolytes (GPEs), 50-200 g/bottle, CGPECMEOEOEA

EOEOEA {2-(2-Ethoxyethoxy)ethyl acrylate, >99.0%} as Crosslinking Monomer for Gel Polymer Electrolytes (GPEs), 50-200 g/bottle, CGPECMEOEOEA

$79.00 USD
In Stock SKU: CGPECMEOEOEA50
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EOEOEA (2-(2-Ethoxyethoxy)ethyl acrylate) (C9H16O4) is a flexible, long-chain monofunctional acrylate monomer featuring an ethoxyethoxyethyl oligo(ethylene glycol) ether side chain attached to a reactive acrylate group. While multifunctional crosslinkers provide primary 3D network connectivity, EOEOEA is utilized in advanced energy storage research as a specialized, highly flexible functional co-monomer and reactive diluent for Gel Polymer Electrolytes (GPEs) and solid-state polymer electrolyte systems. It combines low liquid viscosity with PEO-like ether oxygen linkages that actively assist in alkali metal ion solvation and local chain segmental motion.

Its main structural features are: (1) Oligo-Ether Side Chain Architecture: Features a recurring ether-oxygen sequence (-CH2CH2OCH2CH2OCH2CH3) that structurally mimics short segments of polyethylene oxide (PEO). This local chemical environment promotes Lewis acid-base coordination with lithium (Li+) or sodium (Na+) ions. (2) Low Liquid Viscosity & Reactive Dilution: Possesses very low room-temperature viscosity and high boiling characteristics, functioning as an efficient reactive diluent that dissolves readily in aprotic carbonate binary/ternary solvent blends (EC/DEC/DMC/PC) and thoroughly wets porous separator membranes (glass fiber, PE/PP) and dense electrode microstructures prior to curing. (3) Exceptional Chain Flexibility & Low Tg: The flexible ethoxyethoxyethyl tail imparts a very low glass transition temperature (Tg) to the resulting polymer chains, enhancing amorphous domain mobility and preventing embrittlement during prolonged charge-discharge cycling. (4) Rapid Acrylate Polymerization Kinetics: As an acrylate derivative, EOEOEA exhibits fast free-radical propagation rates under thermal or UV activation, ensuring efficient copolymerization into the growing 3D polymer network.

Its main features are: (1) Rigid 3D Network & Complete Liquid Immobilization: DPHA rapidly copolymerizes into a tight, highly branched mesh that permanently traps and immobilizes organic liquid electrolytes (EC/DEC/DMC/PC), completely eliminating free-flowing liquid leakage and suppressing solvent volatility. (2) Superior Mechanical Dendrite Suppression: Because soft, flexible linear polymer matrices can sometimes lack the high shear modulus required to physically block aggressive lithium or sodium dendrite growth, incorporating DPHA as a high-density crosslinker substantially elevates the mechanical hardness and puncture resistance of the GPE. (3) Enhanced Dimensional Stability Under Cycling: The rigid 3D architecture restrains volumetric expansion and contraction at the electrode interfaces during prolonged cycling, preventing micro-cracking and maintaining continuous interfacial contact.

The main functional roles in GPEs are: (1) Enhanced Ionic Conduction via Ether-Oxygen Solvation: The ether linkages within the ethoxyethoxyethyl side chain act as electron-donating coordination sites that interact dynamically with charge-carrying cations. This assists in salt dissociation, lowers desolvation energy, and promotes segmental chain motion, ensuring that EOEOEA-modified GPE networks maintain high room-temperature ionic conductivities routinely exceeding 10^{-3} S/cm. (2) Superior Interfacial Wetting & Adhesion: Due to its low surface tension and high polarity, EOEOEA radically improves the wetting behavior of liquid electrolyte precursors on high-loading composite cathodes (such as NCM811) and alkali metal anodes, minimizing interfacial resistance and eliminating dry-out. (3) Copolymerization Network Modification & Stress Relief: Because EOEOEA is monofunctional (f = 1), it cannot form a 3D network on its own. When copolymerized alongside multi-functional structural crosslinkers (such as HDDA, DPGDA, THEICTA, or DPHA) and ion-conducting macromers (like PEGMA or host polymers such as PVDF-HFP), it acts as a flexible spacer that relieves internal mechanical stress and prevents micro-cracking during electrode volume fluctuations.

Part Number

CGPECMEOEOEA (C-GPE-CM-EOEOEA)

CAS

7328-17-8

Chemical Formula

 C₉H₁₆O₄

Molecular Weight

188.22 g/mol

Appearance

Colorless liquid

Purity 

>99.0%

Density

1.03 g/mL

Viscosity

3-10 cps

Package Size 50 g, 100 g, and 200 g/bottle


Notes: Please try to store the EOEOEA liquid in a dry place and dark place.

References: 

  1. C. Liu, et al. In Situ Construction of Zwitterionic Polymer Electrolytes with Synergistic Cation–Anion Regulation Functions for Lithium Metal Batteries, Adv. Funct. Mater., 2024, 34, 2307248
  2. Z. Qiu, et al. Surface activated polyethylene separator promoting Li+ ion transport in gel polymer electrolytes and cycling stability of Li-metal anode, Chemical Engineering Journal, 2019, 368, 321-330

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