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OFPA {2,2,3,3,4,4,5,5-Octafluoropentyl acrylate, OFA, >98%} as Fluorinated Monomer for Gel Polymer Electrolytes (GPEs), 50-200 g/bottle, CGPEFMOFPA

OFPA {2,2,3,3,4,4,5,5-Octafluoropentyl acrylate, OFA, >98%} as Fluorinated Monomer for Gel Polymer Electrolytes (GPEs), 50-200 g/bottle, CGPEFMOFPA

$89.00 USD
In Stock (Ships 3~8 Days) SKU: CGPEFMOFPA50
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Using OFPA (2,2,3,3,4,4,5,5-Octafluoropentyl acrylate) as a functional fluorinated monomer in Gel Polymer Electrolytes (GPEs) introduces unique physicochemical advantages for high-voltage and high-safety lithium or sodium metal batteries.

Its main structural features are: (1) Fluorinated Segments & Low Surface Energy: The flexible fluorinated alkyl side chain (-CH2(CF2)4H) imparts high hydrophobicity and low surface energy, which assists in forming a robust, fluorine-rich Solid Electrolyte Interphase (SEI) on reactive metal anodes (such as lithium or sodium). (2) Enhanced Thermal Stability & Flame Retardancy: The high fluorine content naturally suppresses the flammability of the polymer network, mitigating thermal runaway risks compared to conventional hydrocarbon-only acrylate matrices (like PMMA or PEGDA). (3) Plasticizer Compatibility: The acrylate reactive group (CH2=CH-COO-) allows for facile radical or UV-induced polymerization, while the perfluorinated tail efficiently accommodates and immobilizes polar carbonate or ether plasticizers (EC/DMC/EMC or DOL/DME) without phase separation.

The main functional roles in GPEs are: (1) High Oxidation Stability: The electron-withdrawing nature of the octafluoropentyl groups lowers the HOMO energy level of the resulting polymer network, expanding the electrochemical stability window beyond 4.5 V vs. Li/Li+, making it suitable for high-voltage cathodes (like NMC811 or high-nickel layered oxides). (2) Suppression of Dendrite Growth: The uniform, mechanically resilient cross-linked fluorogel network effectively buffers volumetric changes during stripping/plating cycles and inhibits lithium dendrite penetration.

Part Number

CGPEFMOFPA (C-GPE-FM-OFPA)

CAS

376-84-1

Chemical Formula

 C8H6F8O2

Molecular Weight

286.12 g/mol

Appearance

Colorless liquid

Purity 

>98%

Density

1.481 g/cm3

Flash Point

71 °C

Package Size 50 g, 100 g, and 200 g/bottle


Notes: Please try to store the OFPA liquid in a dry place and dark place.

References: 

  1. Z. Wang, et al. Ionic-Ligand-Assisted Transport in Fluorinated Poly(ionic liquid) Electrolytes Enables 515 Wh Kg−1 Solid-State Lithium Metal Batteries, Adv. Mater., 2026, DOI: 10.1002/adma.75524
  2. H. Xu, et al. Facile engineering of fluoropolymer hydrogels enabling high-efficiency lithium extraction from salt lake brines, Separation and Purification Technology, 2026, 402, 138712

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